(E)-1-溴-2-碘乙烯合成路线 (共 12 条)
反应条件
1: para-bromobenzonitrile With tert.-butyl lithium in diethyl ether; pentane
T=-78°C; 0.5 h;
2: With zinc dibromide in tetrahydrofuran; diethyl ether; pentane
T=-78 - 0°C; 0.5 h;
3: 1-bromo-2-iodoethylene With trifuran-2-yl-phosphane; Cl2Pd[bis(2-diphenylphosphinophenyl)ether]; diisobutylaluminium hydride in tetrahydrofuran; diethyl ether; hexane
T=0°C; 4 h;
参考文献
Qian, Mingxing; Huang, Zhihong; Negishi, Ei-Ichi
Organic Letters, 2004 , vol. 6, # 10 p. 1531 - 1534
参考文献
Viehe; Franchimont Chemische Berichte, 1963 , vol. 96, p. 3153,3157