5-Alpha-胆甾烷-3-酮 合成路线 (共 116 条)
参考文献
Bulletin de la Societe Chimique de France, , vol. <4> 53, p. 581,584
反应条件
pyridine; oxygen; acetic acid; zinc; iron in water 5 h; Ambient temperatureGif system; Further byproducts given;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 1797 - 1804
反应条件
pyridine; oxygen; acetic acid; zinc; iron in water 5 h; Ambient temperatureGif system; Further byproducts given;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 1797 - 1804
反应条件
pyridine; oxygen; acetic acid; zinc; iron in water 5 h; Ambient temperatureGif system; Further byproducts given;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 1797 - 1804
反应条件
pyridine; oxygen; acetic acid; zinc; iron in water 5 h; Ambient temperatureGif system; Further byproducts given;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 1797 - 1804
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反应条件
154212-56-3 铵5-[(Z)-1-(3-羧基-5-氯-4-羟基苯基)-4-[(3S,10S,13R,17R)-10,13-二甲基-17-(6-甲基庚烷-2-基)-2,3,4,5,6,7,8,9,11,12,14,15,16,17-十四氢-1H-环戊二烯并[a]菲-3-基]丁-1-烯基]-3-氯-2-羟基苯甲酸酯
反应条件
1: 1.) n-butyllithium / 1.) DME, hexane, 80 min, 2.) DME, hexane, 60 deg C, 22 h 2: 1.) H2, 2.) tetrabutylammonium fluoride / 1.) platinum oxide / 1.) ethyl acetate, 50 deg C, 4 h 2.) THF, RT, 1 h View Scheme
参考文献
Cushman, Mark; Golebiewski, W. Marek; McMahon, James B.; Buckheit, Robert W.; Clanton, David J.; et al.
Journal of Medicinal Chemistry, 1994 , vol. 37, # 19 p. 3040 - 3050
反应条件
1: LiAlD4; diethyl ether 3: lithium tetradeuterioalanate; diethyl ether View Scheme
参考文献
Corey et al.
Journal of the American Chemical Society, 1956 , vol. 78, p. 5036,5039
反应条件
sodium methylate; benzene
参考文献
Djerassi,C. et al.
Journal of the American Chemical Society, 1960 , vol. 82, p. 5488 - 5493
反应条件
diethyl ether; sodium T=20°C;
参考文献
Stiller; Rosenheim
Journal of the Chemical Society, 1938 , p. 353,355
Full Text Show Details
CIBA
Patent: US2281622 , 1938 ;
反应条件
potassium tert-butylate in tetrahydrofuran
参考文献
Huynh,C.; Julia,S.
Bulletin de la Societe Chimique de France, 1971 , p. 4402 - 4407