5-Alpha-胆甾烷-3-酮合成路线 (共 116 条)
→
566-91-6(8S,9S,10S,13R,14S,17R)-10,13-二甲基-17-[(2R)-6-甲基庚烷-2-基]-6,7,8,9,11,12,14,15,16,17-十氢环戊烯并[a]菲-3-酮+
反应条件
diphenyl diselenide; 3-iodylbenzoic acid in tetrahydrofuran T=20°C; 24 h; Yields of byproduct given;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 463 - 468
反应条件
1: 92 percent / CuBr2 2: 20 percent / CaCO3 / dimethylformamide / 0.5 h / Heating View Scheme
参考文献
Win, War War; Franck, Richard W.
Journal of Organic Chemistry, 1997 , vol. 62, p. 4510 - 4512
反应条件
lithium tri-t-butoxyaluminum hydride in tetrahydrofuran T=25°C; 0.0833333 h; Yields of byproduct given;
参考文献
Tetrahedron, , vol. 36, p. 2977 - 2981
反应条件
ammonia; hydrogen; ruthenium in ethanol T=50°C; P=6 Torr; 4 h;
参考文献
Tetrahedron, , vol. 61, # 8 p. 2105 - 2109
反应条件
c-PentMgBr in tetrahydrofuran T=20°C; 3 h;
参考文献
Chemistry - A European Journal, , vol. 15, # 7 p. 1713 - 1722
参考文献
Journal of the American Chemical Society, , vol. 61, p. 1992,1998
反应条件
magnesium 1.) Et2O, 2.) Et2O, 2 h, room temperature; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , # 21 p. 2917 - 2924
反应条件
T=36°C; untersucht wurde das Mengenverhaeltnis;
参考文献
Journal of the American Chemical Society, , vol. 73, p. 5824
反应条件
T=25°C; Rate constant;
参考文献
Canadian Journal of Chemistry, , vol. 36, p. 1049
参考文献
Journal of Organic Chemistry, , vol. 13, p. 455,457