三甲基(1-(三甲基硅烷基)乙烯基)硅烷合成路线 （共 26 条）
反应条件
silver nitrate; triethylamine; triphenylphosphine; palladium diacetate in dimethyl sulfoxide T=100°C; Heck coupling; 24 h;
参考文献
Pawluc, Piotr; Hreczycho, Grzegorz; Marciniec, Bogdan
Journal of Organic Chemistry, 2006 , vol. 71, # 22 p. 8676 - 8679
反应条件
(i) Br2, CCl4, (ii) NaHCO3, MeOH; Multistep reaction;
参考文献
Groebel,B.-T.; Seebach,D.
Chemische Berichte, 1977 , vol. 110, p. 867 - 877
反应条件
1,8-diazabicyclo[5.4.0]undec-7-ene in N,N-dimethyl-formamide
T=90°C; 8 h;
参考文献
Inoue, Atsushi; Kondo, Junichi; Shinokubo, Hiroshi; Oshima, Koichiro
Chemistry Letters, 2001 , # 10 p. 956 - 957
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Inoue, Atsushi; Kondo, Junichi; Shinokubo, Hiroshi; Oshima, Koichiro
Chemistry - A European Journal, 2002 , vol. 8, # 7 p. 1730 - 1740
反应条件
1: 1,2-bis(dimethylvinylsilyloxy)ethane With carbonylchlorohydridetris(triphenylphosphine) ruthenium(II)
T=120°C; 2 h;
2: methyl-magnesium iodide in tetrahydrofuran
T=65°C; 18 h;
参考文献
Pawluc, Piotr; Hreczycho, Grzegorz; Marciniec, Bogdan
Journal of Organic Chemistry, 2006 , vol. 71, # 22 p. 8676 - 8679
反应条件
RuCl(CO)(triphenylphosphine)2(SiMe3) in benzene
T=130°C; 48 h;
参考文献
Marciniec, Bogdan; Pietraszuk, Cezary
Journal of the Chemical Society, Chemical Communications, 1995 , # 19 p. 2003 - 2004
反应条件
in tetrahydrofuran
T=65°C; 24 h;
参考文献
Pawluc, Piotr; Marciniec, Bogdan; Hreczycho, Grzegorz; Gaczewska, Beata; Itami, Yujiro
Journal of Organic Chemistry, 2005 , vol. 70, # 1 p. 370 - 372
反应条件
sodium hydride in tetrahydrofuran
3 h; Heating;
参考文献
Pan, Ming; Benneche, Tore
Acta Chemica Scandinavica, 1998 , vol. 52, # 9 p. 1141 - 1143
反应条件
zinc dibromide in dichloromethane
72 h;
参考文献
Fleming, Ian; Floyd, Christopher D.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 969 - 976
反应条件
1.1: MeMgBr / tetrahydrofuran; diethyl ether / 0.5 h / -78 °C
1.2: 89 percent / tetrahydrofuran; diethyl ether / 0.5 h / -78 °C
2.1: 83 percent / DBU / dimethylformamide / 8 h / 90 °C
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参考文献
Inoue, Atsushi; Kondo, Junichi; Shinokubo, Hiroshi; Oshima, Koichiro
Chemistry - A European Journal, 2002 , vol. 8, # 7 p. 1730 - 1740
反应条件
boron trichloride in dichloromethane
T=-78°C; 1 h;
参考文献
Fleming, Ian; Floyd, Christopher D.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 969 - 976
