in gaseous matrix a 2percent mixture of N2 in Ar passed through discharge tube seeded with sulfur vapor in equilibrium with the solid at 25°C-115°C; trappening in solid Ar; not isolated, detected by IR; influence of annealing on product-distribution;

in neat (no solvent) byproducts: benzonitrile; flash vac. pyrolysis in unpacked quartz tubes at temps. from 200 - 700°C (1E-4 mbar);; isolating the products in Ar or Xe matrices at 12 - 20 K or neat at 77 K;

in neat (no solvent) byproducts: benzonitrile-d5; flash vac. pyrolysis in unpacked quartz tubes at temps. from 200 - 700°C (1E-4 mbar); isolating the products in Ar or Xe matrices at 12 - 20 K or neat at 77 K;

in neat (no solvent) byproducts: 4-methylbenzonitrile; flash vac. pyrolysis in unpacked quartz tubes at temps. from 200 - 700°C (1E-4 mbar);; isolating the products in Ar or Xe matrices at 12 - 20 K or neat at 77 K;

in neat (no solvent) byproducts: phenyl cyanate; flash vac. pyrolysis in unpacked quartz tubes at temps. from 200 - 700°C (1E-4 mbar);; isolating the products in Ar or Xe matrices at 12 - 20 K or neat at 77 K;

in neat (no solvent) byproducts: 2-methylbenzonitrile; flash vac. pyrolysis in unpacked quartz tubes at temps. from 200 - 700°C (1E-4 mbar);; isolating the products in Ar or Xe matrices at 12 - 20 K or neat at 77 K;