1: With 1,3-bis-(diphenylphosphino)propane; triethylamine; bis(dibenzylideneacetone)-palladium(0) in N,N-dimethyl-formamide T=80°C; Heck reaction; 24 h; 2: With hydrogenchloride in N,N-dimethyl-formamide T=20°C; 24 h;
1: With triphenylphosphine; bis(dibenzylideneacetone)-palladium(0) in tetrahydrofuran T=70°C; Negishi coupling reaction; 48 h; 2: With hydrogenchloride in tetrahydrofuran T=20°C; 24 h;
1: With triphenylphosphine; bis(dibenzylideneacetone)-palladium(0) in tetrahydrofuran T=70°C; Negishi coupling reaction; 48 h; 2: With hydrogenchloride in tetrahydrofuran T=20°C; 24 h;