2,2-二甲基-1,3-环己烷二酮合成路线 (共 36 条)
反应条件
in water
T=30°C; 48 h; fermentation, baker's yeast;
参考文献
Yanai, Makoto; Sugai, Takeshi; Mori, Kenji
Agricultural and Biological Chemistry, 1985 , vol. 49, # 8 p. 2373 - 2378
反应条件
N,N-diethylaniline; benzo[1,3,2]dioxaborole in toluene
T=-60°C; 4 h; Title compound not separated from byproducts.;
参考文献
Yeung, Ying-Yeung; Chein, Rong-Jie; Corey
Journal of the American Chemical Society, 2007 , vol. 129, # 34 p. 10346 - 10347
反应条件
Kloeckera magna (ATCC 20109); sodium chloride in N,N-dimethyl-formamide
14 h;
参考文献
Ema, Tadashi; Yagasaki, Hideo; Okita, Nobuyasu; Takeda, Masahiro; Sakai, Takashi
Tetrahedron, 2006 , vol. 62, # 26 p. 6143 - 6149
反应条件
(S)-oxazaborolidine; benzo[1,3,2]dioxaborole in toluene
T=-78°C;
参考文献
Corey; Houpis, Loannis N.
Journal of the American Chemical Society, 1990 , vol. 112, # 24 p. 8997 - 8998
反应条件
sodium tetrahydroborate in methanol
T=0°C;
参考文献
Laverde Jr., Antonio; Da Conceicao, Gelson J. A.; Queiroz, Sonia C. N.; Fujiwara, Fred Y.; Marsaioli, Anita J.
Magnetic Resonance in Chemistry, 2002 , vol. 40, # 7 p. 433 - 442
反应条件
n-butyllithium
1.) THF, -70 deg C, 10h, 2.) RT, 36h; Yield given. Multistep reaction;
参考文献
Yamamoto, Yoshinori; Furuta, Toshiaki
Journal of Organic Chemistry, 1990 , vol. 55, # 13 p. 3971 - 3972