3-[1,1'-联苯]-4-基-1-溴-1,2,3,4-四氢萘合成路线 (共 7 条)
反应条件
phosphorus tribromide in dichloromethane
T=0°C;
参考文献
Van Heerden, Pieter S.; Bezuidenhoudt, Barend C. B.; Ferreira, Daneel
Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 8 p. 1141 - 1146
反应条件
1: NaBH4
2: PBr3
3: (i) NaH, DMF, (ii) /BRN= 2117276/, (iii) aq. NaOH, EtOH
4: polyphosphoric acid / 160 - 170 °C
5: NaBH4
6: PBr3
View Scheme
参考文献
Shadbolt; Woodward; Birchwood
Journal of the Chemical Society. Perkin transactions 1, 1976 , # 11 p. 1190 - 1195
反应条件
1: NaBH4
2: PBr3
View Scheme
参考文献
Shadbolt; Woodward; Birchwood
Journal of the Chemical Society. Perkin transactions 1, 1976 , # 11 p. 1190 - 1195
反应条件
1: polyphosphoric acid / 160 - 170 °C
2: NaBH4
3: PBr3
View Scheme
参考文献
Shadbolt; Woodward; Birchwood
Journal of the Chemical Society. Perkin transactions 1, 1976 , # 11 p. 1190 - 1195
反应条件
1: PBr3
2: (i) NaH, DMF, (ii) /BRN= 2117276/, (iii) aq. NaOH, EtOH
3: polyphosphoric acid / 160 - 170 °C
4: NaBH4
5: PBr3
View Scheme
参考文献
Shadbolt; Woodward; Birchwood
Journal of the Chemical Society. Perkin transactions 1, 1976 , # 11 p. 1190 - 1195
反应条件
1: (i) NaH, DMF, (ii) /BRN= 2117276/, (iii) aq. NaOH, EtOH
2: polyphosphoric acid / 160 - 170 °C
3: NaBH4
4: PBr3
View Scheme
参考文献
Shadbolt; Woodward; Birchwood
Journal of the Chemical Society. Perkin transactions 1, 1976 , # 11 p. 1190 - 1195
反应条件
hydrogenchloride
T=160°C; 0.5 h; Yield given. Yields of byproduct given;
参考文献
Van Heerden, Pieter S.; Bezuidenhoudt, Barend C. B.; Ferreira, Daneel
Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 8 p. 1141 - 1146