3-[1,1'-联苯]-4-基-3,4-二氢萘-1(2H)-酮合成路线 (共 9 条)
反应条件
aluminium trichloride in toluene
T=90°C; 16 h;
参考文献
Van Heerden, Pieter S.; Bezuidenhoudt, Barend C. B.; Ferreira, Daneel
Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 8 p. 1141 - 1146
参考文献
Shadbolt; Woodward; Birchwood
Journal of the Chemical Society. Perkin transactions 1, 1976 , # 11 p. 1190 - 1195
反应条件
1: 1.) CuI, TMEDA, 2.) TMSCl / 1.) THF, -78 deg C, 15 min, -30 deg C, 24 h
2: 88 percent / AlCl3 / toluene / 16 h / 90 °C
View Scheme
参考文献
Van Heerden, Pieter S.; Bezuidenhoudt, Barend C. B.; Ferreira, Daneel
Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 8 p. 1141 - 1146
反应条件
1: 1.) CuI, TMEDA, 2.) TMSCl / 1.) THF, -78 deg C, 15 min, -30 deg C, 24 h
2: 88 percent / AlCl3 / toluene / 16 h / 90 °C
View Scheme
参考文献
Van Heerden, Pieter S.; Bezuidenhoudt, Barend C. B.; Ferreira, Daneel
Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 8 p. 1141 - 1146
反应条件
1: NaBH4
2: PBr3
3: (i) NaH, DMF, (ii) /BRN= 2117276/, (iii) aq. NaOH, EtOH
4: polyphosphoric acid / 160 - 170 °C
View Scheme
参考文献
Shadbolt; Woodward; Birchwood
Journal of the Chemical Society. Perkin transactions 1, 1976 , # 11 p. 1190 - 1195
反应条件
1: PBr3
2: (i) NaH, DMF, (ii) /BRN= 2117276/, (iii) aq. NaOH, EtOH
3: polyphosphoric acid / 160 - 170 °C
View Scheme
参考文献
Shadbolt; Woodward; Birchwood
Journal of the Chemical Society. Perkin transactions 1, 1976 , # 11 p. 1190 - 1195
反应条件
1: (i) NaH, DMF, (ii) /BRN= 2117276/, (iii) aq. NaOH, EtOH
2: polyphosphoric acid / 160 - 170 °C
View Scheme
参考文献
Shadbolt; Woodward; Birchwood
Journal of the Chemical Society. Perkin transactions 1, 1976 , # 11 p. 1190 - 1195
反应条件
1: NaBH4
2: 160 - 170 °C
View Scheme
参考文献
Shadbolt; Woodward; Birchwood
Journal of the Chemical Society. Perkin transactions 1, 1976 , # 11 p. 1190 - 1195
反应条件
1: NaBH4
2: PBr3
View Scheme
参考文献
Shadbolt; Woodward; Birchwood
Journal of the Chemical Society. Perkin transactions 1, 1976 , # 11 p. 1190 - 1195