(4E)-1,4-十一碳二烯合成路线 （共 20 条）
反应条件
perchloric acid in diethyl ether
T=0°C; 0.1 h;
参考文献
Wilson, Stephen R.; Zucker, Paul A.
Journal of Organic Chemistry, 1988 , vol. 53, # 20 p. 4682 - 4693
反应条件
oxygen; dichloro bis(acetonitrile) palladium(II) in N,N-dimethyl-formamide
Ambient temperature;
参考文献
Alcaraz, Lilian; Taylor, Richard J. K.
Synlett, 1997 , vol. 1997, # 7 p. 791 - 792
反应条件
tris(dibenzylideneacetone)dipalladium (0) in tetrahydrofuran
T=50°C; 2 h;
参考文献
Nakao, Yoshiaki; Ebata, Shiro; Chen, Jinshui; Imanaka, Hidekazu; Hiyama, Tamejiro
Chemistry Letters, 2007 , vol. 36, # 5 p. 606 - 607
反应条件
ammonium sulfate; ammonia; water; lithium
0.1 h;
参考文献
Brandsma, Lambert; Nieuwenhuizen, Willem F.; Zwikker, Jan W.; Maeeorg, Uno
European Journal of Organic Chemistry, 1999 , # 4 p. 775 - 779
反应条件
ammonium sulfate; ammonia; water; lithium
0.1 h;
参考文献
Brandsma, Lambert; Nieuwenhuizen, Willem F.; Zwikker, Jan W.; Maeeorg, Uno
European Journal of Organic Chemistry, 1999 , # 4 p. 775 - 779
反应条件
benzo[1,3,2]dioxaborole
2.) THF, RT, 5 h; Yield given. Multistep reaction;
参考文献
Miyaura, Norio; Yamada, Kinji; Suginome, Hiroshi; Suzuki, Akira
Journal of the American Chemical Society, 1985 , vol. 107, # 4 p. 972 - 980
反应条件
1: 1.) magnesium / 1.) ether, 2.) RT, 15 min
2: triethylamine / CH2Cl2 / 0.08 h / 0 °C
3: triethylamine / CH2Cl2 / 0.33 h / Ambient temperature
View Scheme
参考文献
Wilson, Stephen R.; Zucker, Paul A.
Journal of Organic Chemistry, 1988 , vol. 53, # 20 p. 4682 - 4693
反应条件
1: 86 percent / LAH / diethyl ether / 0.5 h / 0 °C
2: 71 percent / pyridinium chlorochromate (PCC) / CH2Cl2 / 0 °C
3: 1.) magnesium / 1.) ether, 2.) RT, 15 min
4: triethylamine / CH2Cl2 / 0.08 h / 0 °C
5: triethylamine / CH2Cl2 / 0.33 h / Ambient temperature
View Scheme
参考文献
Wilson, Stephen R.; Zucker, Paul A.
Journal of Organic Chemistry, 1988 , vol. 53, # 20 p. 4682 - 4693
反应条件
1: 71 percent / pyridinium chlorochromate (PCC) / CH2Cl2 / 0 °C
2: 1.) magnesium / 1.) ether, 2.) RT, 15 min
3: triethylamine / CH2Cl2 / 0.08 h / 0 °C
4: triethylamine / CH2Cl2 / 0.33 h / Ambient temperature
View Scheme
参考文献
Wilson, Stephen R.; Zucker, Paul A.
Journal of Organic Chemistry, 1988 , vol. 53, # 20 p. 4682 - 4693
反应条件
1: 1.) magnesium / 1.) ether, 2.) RT, 15 min
2: triethylamine / CH2Cl2 / 0.08 h / 0 °C
3: triethylamine / CH2Cl2 / 0.33 h / Ambient temperature
View Scheme
参考文献
Wilson, Stephen R.; Zucker, Paul A.
Journal of Organic Chemistry, 1988 , vol. 53, # 20 p. 4682 - 4693
