in pentane suspn. of Li(N(C2H5)2) is cooled in pentane to 223 K, dropwise addn. of VOCl2(OCH(CH3)2) during 15 min, warming to room temp.; remove of the solvent in vac.;
in isopropyl alcohol after A. Lachowicz, W. Hoebold, K.-H. Thiele, Z. Anorg. Allg. Chem. 418 (1975) 65, refluxed; removal of solvent, fractional distillation under high vacuum;
Dinachali, Saman Safari; Saifullah, Mohammad S. M.; Ganesan, Ramakrishnan; Thian, Eng San; He, Chaobin
Advanced Functional Materials, 2013 , vol. 23, # 17 p. 2201 - 2211
hydrogenchloride in pentane pumping HCl through soln. of trialkoxide at ambient temp. for 12 s yielded monochloride; pumping HCl for 30 s yielded dichloride; monitoring by 51V-NMR;
参考文献
Crans, Debbie C.; Chen, Haojiang; Felty, Robert A.
Journal of the American Chemical Society, 1992 , vol. 114, # 12 p. 4543 - 4550
