2,3,4,5-四氟硝基苯合成路线 （共 21 条）
反应条件
sulfuric acid; nitric acid
参考文献
Tetrahedron, , vol. 23, p. 4719 - 4727
反应条件
t-Bu-XantPhos; tBuXantphosAu(AuCl2); (Ph)2SiH2; acetic acid in 1,2-dichloro-ethane T=80°C; 24 h; Inert atmosphere;
参考文献
Advanced Synthesis and Catalysis, , vol. 354, # 8 p. 1529 - 1541
反应条件
XantphosAuCl; Xantphos; (Ph)2SiH2; trifluoroacetic acid in 1,2-dichloro-ethane T=80°C; 24 h; Inert atmosphere;
参考文献
Advanced Synthesis and Catalysis, , vol. 354, # 8 p. 1529 - 1541
反应条件
[Cu(I)(CH3CN)4]PF6; dimethylphenylsilane; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene in toluene 12 h; Inert atmosphereReflux; Catalytic behavior; SolventReagent/catalyst; regioselective reaction;
参考文献
Angewandte Chemie - International Edition, , vol. 52, # 11 p. 3203 - 3207
Angew. Chem., , vol. 125, # 11 p. 3285 - 3289,5
反应条件
hydrogenchloride; tin
参考文献
Coe,P.L. et al.
Journal of the Chemical Society [Section] C: Organic, 1966 , p. 2323 - 2324
反应条件
t-Bu-XantPhos; tBuXantphosAu(AuCl2); (Ph)2SiH2; acetic acid in 1,2-dichloro-ethane T=80°C; 24 h; Inert atmosphere;
参考文献
Lv, Hongbin; Cai, Yuan-Bo; Zhang, Jun-Long
Angewandte Chemie - International Edition, 2013 , vol. 52, # 11 p. 3203 - 3207
Angew. Chem., 2013 , vol. 125, # 11 p. 3285 - 3289,5
反应条件
palladium monocarbide
参考文献
Wang, Yuncai; Chen, Rongye; Nan, Haijun
Patent: US2003/166936 A1, 2003 ;
反应条件
1: 99 percent / methanol / Ambient temperature 2: 99.8 percent / H2 / Pd/C / ethanol; ethyl acetate / 2068.6 Torr 3: 1.) NaNO2, HCl, 2.) H3PO2 / 1.) H2O, 15 min, 2.) H2O, 4 deg C, overnight, 20 deg C, 2 h 4: 90 percent / BBr3 / CH2Cl2 View Scheme
参考文献
Pedersen, Stephan K.; Holmehave, Jeppe; Blaikie, Frances H.; Gollmer, Anita; Breitenbach, Thomas; Jensen, Henrik H.; Ogilby, Peter R.
Journal of Organic Chemistry, 2014 , vol. 79, # 7 p. 3079 - 3087
反应条件
XeF2; hydrogen fluoride 0.416667 h; Ambient temperature; Further byproducts given. Title compound not separated from byproducts;
参考文献
Journal of Fluorine Chemistry, , vol. 77, # 2 p. 153 - 159
反应条件
4-(N,N-dimethlyamino)pyridine; C21H27AuN2 in dichloromethane T=40°C; 12 h; Inert atmosphere;
参考文献
Lv, Hongbin; Zhan, Jin-Hui; Cai, Yuan-Bo; Yu, Yi; Wang, Bingwu; Zhang, Jun-Long
Journal of the American Chemical Society, 2012 , vol. 134, # 39 p. 16216 - 16227,12
