hydrogenchloride; nitrosyl chloride T=20°C; 9 h; Irradiation; Further byproducts given;

nitrosyl chloride im Sonnenlicht unter Ausschluss von Sauerstoff;

sodium hydroxide; hydroxylamine

chromium trioxide-kieselghur reagent in dichloromethane 3 h; Reflux;

potassium hydroxide in dimethyl sulfoxide T=20 - 35°C; Etherification; Alkylation; Hydrolysis; 2.5 h;

potassium hydroxide in dimethyl sulfoxide T=20 - 35°C; Etherification; Alkylation; Hydrolysis; 2.5 h;

lithium aluminium tetrahydride; 3-O-cyclohexylmethyl-1,2-O-cyclohexylidene-α-D-glucofuranose in diethyl ether 2.5 h; HeatingLiAlH4 concentration effect on enantiomeric excess; asymmetric reduction of ketones and isoelectronic ketone oximes with LiAlH4-3-O-cyclohexylmethyl-1,2-O-cyclohexylidene-α-D-glucofuranose complex; Product distribution;

lithium aluminium tetrahydride; 3-O-cyclohexylmethyl-1,2-O-cyclohexylidene-α-D-glucofuranose in diethyl ether 2.5 h; HeatingLiAlH4 concentration effect on enantiomeric excess; asymmetric reduction of ketones and isoelectronic ketone oximes with LiAlH4-3-O-cyclohexylmethyl-1,2-O-cyclohexylidene-α-D-glucofuranose complex; Product distribution;

lithium aluminium tetrahydride; 3-O-cyclohexylmethyl-1,2-O-cyclohexylidene-α-D-glucofuranose in diethyl ether 2.5 h; HeatingLiAlH4 concentration effect on enantiomeric excess; asymmetric reduction of ketones and isoelectronic ketone oximes with LiAlH4-3-O-cyclohexylmethyl-1,2-O-cyclohexylidene-α-D-glucofuranose complex; Product distribution;

T=95 - 106°C; 2.5 h; var. time, var. temperatures; Product distribution;