Pd0(tris(tert-butyl)phosphine)2; cesium fluoride in 1,4-dioxane T=130°C; 12 h;

Pd0(tris(tert-butyl)phosphine)2; cesium fluoride in 1,4-dioxane T=60°C; 12 h; Schlenk techniqueInert atmosphere;

Pd0(tris(tert-butyl)phosphine)2 in tetrahydrofuran T=60°C; 12 h;

in toluene byproducts: Me2SnCl2; (Ar); using Schlenk techniques; vac. transferring of toluene into flask with C12H8SnMe2 at -78°C; addn. dropwise via syringe of soln. of C6H5BCl2 at -78°C, slowly warming to room temp., stirring overnight; removal of solvent under vac., transferring to a sublimator, removal of Me2SnCl2 under static vac. at 40°C for 2 days, elem. anal.;

Pd0(tris(tert-butyl)phosphine)2; cesium fluoride in 1,4-dioxane T=60°C; 24 h; Schlenk techniqueInert atmosphere; Temperature;

Pd0(tris(tert-butyl)phosphine)2 in tetrahydrofuran T=60°C; 48 h;

Pd0(tris(tert-butyl)phosphine)2; cesium fluoride in 1,4-dioxane T=60°C; 12 h; Schlenk techniqueInert atmosphere;

Pd0(tris(tert-butyl)phosphine)2; cesium fluoride in 1,4-dioxane T=60°C; 12 h; Schlenk techniqueInert atmosphere;

Pd0(tris(tert-butyl)phosphine)2; cesium fluoride in 1,4-dioxane T=130°C; 12 h; Schlenk techniqueInert atmosphere;

Pd0(tris(tert-butyl)phosphine)2; cesium fluoride in 1,4-dioxane T=60°C; 12 h; Schlenk techniqueInert atmosphere;