in 2-methyl tetrahydrofuran Irradiation (UV/VIS); photoredn. of the Mn(III) complex in MeTHF by irradiation with visible light (440-750 nm) at 25°C; not isolated; detn. by UV/VIS spectral change;
cyclohexene in benzonitrile
Kinetics; byproducts: p-cyanodimethylaniline, cyclohexene epoxide, cyclohexene-3-one; under N2, soln. of Mn-compd. and cyclohexene in PhCN was added to soln.of p-cyanodimethylaniline N-oxide in PhCN at 23.5°C;
参考文献
Powell, Michael F.; Pai, Emil F.; Bruice, Thomas C.
Journal of the American Chemical Society, 1984 , vol. 106, # 11 p. 3277 - 3285