lithium borohydride in tetrahydrofuran T=70°C; 22 h;
参考文献
Ohkata, Katsuo; Tamura, Yukiko; Shetuni, Brandon B.; Takagi, Ryukichi; Miyanaga, Wataru; Kojima, Satoshi; Paquette, Leo A.
Journal of the American Chemical Society, 2004 , vol. 126, # 51 p. 16783 - 16792
potassium carbonate in N,N-dimethyl-formamide
T=20°C; 23 h;
参考文献
Ohkata, Katsuo; Tamura, Yukiko; Shetuni, Brandon B.; Takagi, Ryukichi; Miyanaga, Wataru; Kojima, Satoshi; Paquette, Leo A.
Journal of the American Chemical Society, 2004 , vol. 126, # 51 p. 16783 - 16792
1: 97.1 percent / NaOH / H2O / 0 - 20 °C
2: 100 percent / K2CO3 / dimethylformamide / 23 h / 20 °C
View Scheme
参考文献
Ohkata, Katsuo; Tamura, Yukiko; Shetuni, Brandon B.; Takagi, Ryukichi; Miyanaga, Wataru; Kojima, Satoshi; Paquette, Leo A.
Journal of the American Chemical Society, 2004 , vol. 126, # 51 p. 16783 - 16792
Marquez, Irene R.; Miguel, Delia; Millan, Alba; Marcos, M. Luisa; De Cienfuegos, Luis Alvarez; Campana, Araceli G.; Cuerva, Juan M.
Journal of Organic Chemistry, 2014 , vol. 79, # 4 p. 1529 - 1541
Marquez, Irene R.; Miguel, Delia; Millan, Alba; Marcos, M. Luisa; De Cienfuegos, Luis Alvarez; Campana, Araceli G.; Cuerva, Juan M.
Journal of Organic Chemistry, 2014 , vol. 79, # 4 p. 1529 - 1541
1: triethylamine / dichloromethane / 2 h / 0 - 20 °C
2: nickel dichloride; triphenylphosphine; bis(cyclopentadienyl)titanium dichloride; manganese; chloro-trimethyl-silane / tetrahydrofuran / 16 h / 50 °C / |Inert atmosphere
View Scheme
参考文献
Marquez, Irene R.; Miguel, Delia; Millan, Alba; Marcos, M. Luisa; De Cienfuegos, Luis Alvarez; Campana, Araceli G.; Cuerva, Juan M.
Journal of Organic Chemistry, 2014 , vol. 79, # 4 p. 1529 - 1541
1: triethylamine / dichloromethane / 2 h / 0 - 20 °C
2: nickel dichloride; triphenylphosphine; bis(cyclopentadienyl)titanium dichloride; manganese; chloro-trimethyl-silane / tetrahydrofuran / 16 h / 50 °C / |Inert atmosphere
View Scheme
参考文献
Marquez, Irene R.; Miguel, Delia; Millan, Alba; Marcos, M. Luisa; De Cienfuegos, Luis Alvarez; Campana, Araceli G.; Cuerva, Juan M.
Journal of Organic Chemistry, 2014 , vol. 79, # 4 p. 1529 - 1541
