N,N-二甲基-2-(三氟甲基)-苯胺合成路线 （共 12 条）
反应条件
tris(1,3-divinyl-1,1,3,3-tetramethyldisiloxane)-bis-platinum(0); 1,3-bis-(diphenylphosphino)propane; phenyl silane in anhydrous butyl ether
T=20°C; 18 h; Schlenk techniqueInert atmosphere;
参考文献
Sorribes, Ivan; Junge, Kathrin; Beller, Matthias
Chemistry - A European Journal, 2014 , vol. 20, # 26 p. 7879 - 7883
反应条件
cis-[Ru(dimethyl sulfoxide)4Cl2]; phenyl silane; di-(1-adamantyl)-n-butylphosphine in toluene
T=100°C; P=22502.3 Torr; AutoclaveInert atmosphere;
参考文献
Li, Yuehui; Fang, Xianjie; Junge, Kathrin; Beller, Matthias
Angewandte Chemie - International Edition, 2013 , vol. 52, # 36 p. 9568 - 9571
Angew. Chem., 2013 , vol. 125, # 36 p. 9747 - 9750,4
反应条件
[bis(acetoxy)iodo]benzene; silver fluoride in dimethyl sulfoxide
T=20°C; 20 h; Overall yield = 75 percent;
参考文献
Seo, Sangwon; Taylor, John B.; Greaney, Michael F.
Chemical Communications, 2013 , vol. 49, # 57 p. 6385 - 6387
反应条件
n-butyllithium in diethyl ether; hexane
参考文献
Hepworth,J.D. et al.
Synthesis, 1974 , p. 874 - 876
反应条件
1: (i) NaNO2, aq. HBr, (ii) CuBr
2: nBuLi / diethyl ether; hexane
View Scheme
参考文献
Hepworth,J.D. et al.
Synthesis, 1974 , p. 874 - 876
反应条件
1: ethanol
2: SnCl2 / ethanol
3: (i) NaNO2, aq. HBr, (ii) CuBr
4: nBuLi / diethyl ether; hexane
View Scheme
参考文献
Hepworth,J.D. et al.
Synthesis, 1974 , p. 874 - 876
反应条件
1: SnCl2 / ethanol
2: (i) NaNO2, aq. HBr, (ii) CuBr
3: nBuLi / diethyl ether; hexane
View Scheme
参考文献
Hepworth,J.D. et al.
Synthesis, 1974 , p. 874 - 876
反应条件
in N,N-dimethyl-formamide
T=140°C; 60 h; Title compound not separated from byproducts;
参考文献
Naumann, D.; Pazenok, S. V.; Turra, V.
Russian Journal of Organic Chemistry, 1993 , vol. 29, # 1.2 p. 128 - 130
Zhurnal Organicheskoi Khimii, 1993 , vol. 29, # 1 p. 152 - 155
反应条件
in N,N-dimethyl-formamide
T=140°C; 60 h; Title compound not separated from byproducts;
参考文献
Naumann, D.; Pazenok, S. V.; Turra, V.
Russian Journal of Organic Chemistry, 1993 , vol. 29, # 1.2 p. 128 - 130
Zhurnal Organicheskoi Khimii, 1993 , vol. 29, # 1 p. 152 - 155
反应条件
in acetonitrile
6 h; Irradiation;
参考文献
Akiyama, Takeo; Kato, Kohji; Kajitani, Masatsugu; Sakaguchi, Yoshio; Nakamura, Junko; et al.
Bulletin of the Chemical Society of Japan, 1988 , vol. 61, p. 3531 - 3538
