4-甲氧基-Alpha-甲基苯丙醛合成路线 （共 14 条）
反应条件
1: With [Ir(acetylacetonate)(1,5-cyclooctadiene)]; triphenylphosphine in N-methylpyrrolidone
T=20 - 100°C; P=5250.53 Torr; Inert atmosphereAutoclave;
2: With hydrogen in N-methylpyrrolidone
T=100°C; P=9750.98 Torr; 16 h; Autoclave; chemoselective reaction;
参考文献
Evonik Oxeno GmbH; Franke, Robert; Beller, Matthias; Jackstell, Ralf; Jennerjahn, Reiko; Piras, Irene
Patent: US2014/24860 A1, 2014 ;
Location in patent: Paragraph 0085 ;
反应条件
ammonium hydrogen carbonate in water; acetonitrile
T=20°C; 3 h;
参考文献
Hofmann, Matthias; Hampel, Nathalie; Kanzian, Tanja; Mayr, Herbert
Angewandte Chemie - International Edition, 2004 , vol. 43, # 40 p. 5402 - 5405
反应条件
hydrogen; N-dodecyl-N-(2-hydroxyethyl)-N,N-dimethylammonium bromide; {Rh(cod)[μ-S(CH2)3Si(OMe)3]}2; triphenylphosphine in water; butan-1-ol
T=80°C; P=10350.8 Torr; 6 h; microemulsion/sol-gel; Further byproducts given;
参考文献
Abu-Reziq, Raed; Avnir, David; Blum, Jochanan
European Journal of Organic Chemistry, 2005 , # 17 p. 3640 - 3642
反应条件
sodium carbonate; [(t-Bu)3PH]BF4; palladium diacetate in 1-methyl-pyrrolidin-2-one; water
T=130°C; 24 h;
参考文献
Scrivanti, Alberto; Bertoldini, Matteo; Beghetto, Valentina; Matteoli, Ugo
Tetrahedron, 2008 , vol. 64, # 3 p. 543 - 548
反应条件
tetrabutyl-ammonium chloride; sodium hydrogencarbonate; palladium diacetate in water
T=80°C; 23 h;
参考文献
Zhao; Cai; Hu; Song
Synthetic Communications, 2001 , vol. 31, # 23 p. 3665 - 3669
反应条件
1: With oxygen; sodium acetate; acetylacetone; palladium diacetate in propionic acid
T=70°C; P=760.051 Torr; 4 h;
2: With hydrogen; palladium on activated charcoal
P=760.051 Torr; Further stages.;
参考文献
Yamada, Tomoyuki; Sakaguchi, Satoshi; Ishii, Yasutaka
Journal of Organic Chemistry, 2005 , vol. 70, # 14 p. 5471 - 5474
反应条件
sodium hydrogencarbonate; palladium diacetate in ethanol
T=60°C; 0.5 h;
参考文献
Barbero, Margherita; Cadamuro, Silvano; Dughera, Stefano
Synthesis, 2006 , # 20 p. 3443 - 3452
反应条件
hydrogen; rhodium(II)bis(2-ethylhexanoate) in water; toluene
T=125°C; P=18751.9 Torr; 10 h;
参考文献
Celanese Chemicals Europe GmbH
Patent: EP1719752 A1, 2006 ;
Location in patent: Page/Page column 6 ;
反应条件
C44H34N4O8P2Rh2S2(2-)*2Na(1+); hydrogen; trimethylhexadecylammonium chloride in water; toluene
T=80°C; P=15526.6 Torr; 8 h; chemoselective reaction;
参考文献
Melean, Luis G.; Rodriguez, Mariandry; Romero, Marynell; Alvarado, Maria L.; Rosales, Merlin; Baricelli, Pablo J.
Applied Catalysis A: General, 2011 , vol. 394, # 1-2 p. 117 - 123
反应条件
C44H34N4O8P2Rh2S2(2-)*2Na(1+); hydrogen; trimethylhexadecylammonium chloride in water; toluene
T=80°C; P=15526.6 Torr; 8 h; chemoselective reaction;
参考文献
Melean, Luis G.; Rodriguez, Mariandry; Romero, Marynell; Alvarado, Maria L.; Rosales, Merlin; Baricelli, Pablo J.
Applied Catalysis A: General, 2011 , vol. 394, # 1-2 p. 117 - 123
