2,4,6-三甲基-2,4,6-三苯基环三硅氧烷合成路线 （共 12 条）
反应条件
H2O in water pouring (CH3)(C6H5)SiCl2 into icewater under vigorous stirring;; distn. at 2 torr; recrystn. from alc.;;
参考文献
Journal of the American Chemical Society, , vol. 70, p. 1115 - 1117
Si: MVol.C, 101, page 276 - 279
反应条件
H2O in diethyl ether; water addn. of H2O to a soln. of (CH3)(C6H5)SiCl2 in ether;;
参考文献
Journal of the American Chemical Society, , vol. 70, p. 3758
Si: MVol.C, 101, page 276 - 279
反应条件
pyridine; sodium hydrogencarbonate in acetone T=20°C; 3 h;
参考文献
Phosphorus, Sulfur and Silicon and the Related Elements, , vol. 178, # 6 p. 1289 - 1294
→
34239-75-32,4,6,8,10-五甲基-2,4,6,8,10-五苯基-1,3,5,7,9,2,4,6,8,10-五氧杂五硅杂环癸烷+
反应条件
water in tetrahydrofuran 10 h; Heating;
参考文献
Unno, Masafumi; Chang, Shengho; Matsumoto, Hideyuki
Bulletin of the Chemical Society of Japan, 2005 , vol. 78, # 6 p. 1105 - 1109
反应条件
water 2 h; Ambient temperature; Further byproducts given;
参考文献
Journal of Organometallic Chemistry, , vol. 428, # 3 p. 315 - 333
反应条件
(i) (hydrolysis), (ii) H2SO4, toluene; Multistep reaction;
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 39, p. 564 - 571,533 - 539
反应条件
in [3.3.1]nonane T=160°C; ΔE(excit.); Rate constantKineticsThermodynamic data;
参考文献
Journal of Organometallic Chemistry, , vol. 212, # 1 p. 43 - 50
参考文献
Voronkov,M.G. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1969 , vol. 39, p. 564 - 571,533 - 539
反应条件
sodium tetrafluoroantimonate(III) 0.5 h; Heating;
参考文献
Farooq, Omar
Journal of Organometallic Chemistry, 2000 , vol. 613, # 2 p. 239 - 243
反应条件
silver(l) oxide; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran T=60°C;
参考文献
Mori; Suguro
Synlett, 2001 , # 6 p. 845 - 847
