2-(2-甲基苯甲酰)吡啶合成路线 (共 5 条)
反应条件
caesium carbonate; 1,3-bis(2,4,6-trimethylphenyl)imidazolinium chloride; palladium diacetate in 1,4-dioxane
T=120°C; P=37503 Torr; 6 h;
参考文献
Maerten, Eddy; Sauthier, Mathieu; Mortreux, Andre; Castanet, Yves
Tetrahedron, 2007 , vol. 63, # 3 p. 682 - 689
反应条件
[Co(O2CCH3)2]*4H2O in 1,4-dioxane
T=50°C; 4.5 h; chemoselective reaction;
参考文献
Karthikeyan; Alamsetti; Sekar
Organometallics, 2014 , vol. 33, # 7 p. 1665 - 1671
反应条件
1: 1-bromo-2-methyl benzene With magnesium in tetrahydrofuran
Inert atmosphere;
2: 2-pyridine carbonitrile in tetrahydrofuran
T=0°C; Inert atmosphere;
3: With hydrogenchloride; water in diethyl ether
0.5 h; Inert atmosphere;
参考文献
Tao, Xiaoming; Li, Wanfang; Ma, Xin; Li, Xiaoming; Fan, Weizheng; Xie, Xiaomin; Ayad, Tahar; Ratovelomanana-Vidal, Virginie; Zhang, Zhaoguo
Journal of Organic Chemistry, 2012 , vol. 77, # 1 p. 612 - 616
反应条件
diethyl ether; benzene
und Erhitzen des Reaktionsgemisches mit wss.Ammoniumchlorid-Loesung;
参考文献
Badger; Pettit
Journal of the Chemical Society, 1953 , p. 2774,2778
反应条件
manganese(IV) oxide
2.) ether; Yield given. Multistep reaction;
参考文献
Schubert, Ralf; Gruetzmacher, Hans-Friedrich
Organic Mass Spectrometry, 1980 , vol. 15, # 3 p. 122 - 130