in diethyl ether
(N2); Schlenk technique; soln. of Fe complex and chloroformate in Et2O was stirred overnight; volatiles removed (vac.); redissolved in CH2Cl2; chromd. (hexane; hexane/CH2Cl2, 1/1); recrystd. (CH2Cl2/hexane); elem. anal.;
参考文献
El-Khateeb, Mohammad
Inorganica Chimica Acta, 2004 , vol. 357, # 14 p. 4341 - 4344
in diethyl ether
under N2, Schlenk techniques; chloroformate added to soln. of iron complex in diethyl ether, stirred overnight; volatiles removed under vac., residue dissolved in CH2Cl2, column chromy. (silica, hexane and hexane/CH2Cl2 1/1), thiocarbonate complex (orange band) recrystd. from CH2Cl2/hexane; elem. anal.;
参考文献
El-khateeb, Mohammad; Asali, Khalil J.; Lataifeh, Anas
Polyhedron, 2003 , vol. 22, # 23 p. 3105 - 3108
