1: With di-isopropylmagnesium; LiDMAE in diethyl ether T=0 - 20°C; Inert atmosphere; 2: With ammonium chloride in diethyl ether; water Inert atmosphere;
参考文献
Saelinger, Daniel; Brueckner, Reinhard
Chemistry - A European Journal, 2009 , vol. 15, # 27 p. 6688 - 6703
sodium hydrogencarbonate; sodium bromide; chiral 4,1'-dinaphthyl-3,2'-cyclo[C(Me)2-N(oxyl)-C(Me)2] in dichloromethane; water T=-15°C; resolution of racemate; 1.5 h; Electrolysis; Title compound not separated from byproducts;
sodium hydrogencarbonate; sodium bromide; chiral 4,1'-dinaphthyl-3,2'-cyclo[C(Me)2-N(oxyl)-C(Me)2] in dichloromethane; water T=-15°C; resolution of racemate; 1.5 h; Electrolysis; Title compound not separated from byproducts;
sodium hydrogencarbonate; sodium bromide; chiral 4,1'-dinaphthyl-3,2'-cyclo[C(Me)2-N(oxyl)-C(Me)2] in dichloromethane; water T=-15°C; resolution of racemate; 1.5 h; Electrolysis; Title compound not separated from byproducts;
