in tetrahydrofuran byproducts: pyridine; 5-mL aliquot of 1E-2 M NaMn(CO)4PPh3 in THF added under Ar to 5 mL of 1E-2 M Mn(CO)5(py)(1+) in THF at 22°C, react. complete within 5 min; not isolated; detected by IR;
in tetrahydrofuran byproducts: pyridine; 5-mL aliquot of 1E-2 M Mn(CO)4PPh3(1-) in THF added under Ar to 5 mL of 1E-2 M Mn(CO)5(py)(1+) in THF at 22°C, react. complete within 5 min; not isolated; detected by IR;
in tetrahydrofuran byproducts: pyridine; Electrolysis; 0.3 M TBAP, constant current 3 mA, electrode potential -1.15 to -1.55 V; not isolated, detected by IR spectroscopy;
in tetrahydrofuran byproducts: pyridine; 5-mL aliquot of 1E-2 M Mn(CO)4P(OPh)3(1-) in THF added under Ar to 5 mL of 1E-2 M Mn(CO)5(py)(1+) in THF at 22°C, react. complete within 5 min; not isolated; detected by IR;
in tetrahydrofuran byproducts: pyridine; 5-mL aliquot of 1E-2 M NaMn(CO)4P(OPh)3 in THF added under Ar to 5 mL of 1E-2 M Mn(CO)5(py)(1+) in THF at 22°C, react. complete within 5 min; not isolated; detected by IR;
in tetrahydrofuran Mn(CO)5(1-) (1.2 M, 5 mL) added under Ar to 5 mL of 1E-2 M Mn(CO)5(C5H5N)(1+), 0.3 M tetra-n-butylammonium perchlorate added, react. time approx. 30 min;
参考文献
Lee, K. Y.; Kuchynka, D. J.; Kochi, J. K.
Organometallics, 1987 , vol. 6, p. 1886 - 1897
