1: With 5-(2-hydroxyethyl)-4-methyl-3-(phenylmethyl)thiazolium chloride; tert-butyl alcohol in tetrahydrofuran T=20°C; 0.0833333 h; Inert atmosphere; 2: With sodium t-butanolate in tetrahydrofuran T=20°C; 12 h; Inert atmosphere; chemoselective reaction;

1: With acetic acid; sodium nitrite in water T=0°C; 1 h; Inert atmosphere; 2: With sodium azide in water T=0 - 20°C; Inert atmosphere;

sodium acetate in (2S)-N-methyl-1-phenylpropan-2-amine hydrate; water; acetic acid; benzene

in decalin T=110.6°C; 1.3 h; Ea, δSa; also in presence of 2,6-di-t-butyl-4-methylphenol; Rate constantKineticsThermodynamic data;