B-苄基-9-硼杂双环[3.3.1]壬烷合成路线 （共 22 条）
反应条件
in diethyl ether T=-78 - 20°C;
参考文献
Fang, Guang Y.; Wallner, Olov A.; Di Blasio, Nadia; Ginesta, Xavier; Harvey, Jeremy N.; Aggarwal, Varinder K.
Journal of the American Chemical Society, 2007 , vol. 129, # 47 p. 14632 - 14639
反应条件
1: 1-(benzylsulfonyl)-3-fluorobenzene With n-butyllithium in tetrahydrofuran; hexane T=-78 - 0°C; 0.5 h; Inert atmosphere; 2: 9-bora-bicyclo[3.3.1]nonane in tetrahydrofuran; hexane T=0 - 20°C; Inert atmosphere;
参考文献
Organic Letters, , vol. 14, # 9 p. 2262 - 2265
反应条件
1.1: potassium hydrogen persulfate / methanol; water / 12 h / 0 - 20 °C / Inert atmosphere 2.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 - 0 °C / Inert atmosphere 2.2: 0 - 20 °C / Inert atmosphere View Scheme
参考文献
Organic Letters, , vol. 14, # 9 p. 2262 - 2265
反应条件
1.1: potassium carbonate / N,N-dimethyl-formamide / 80 °C / Inert atmosphere 2.1: potassium hydrogen persulfate / methanol; water / 12 h / 0 - 20 °C / Inert atmosphere 3.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 - 0 °C / Inert atmosphere 3.2: 0 - 20 °C / Inert atmosphere View Scheme
参考文献
Organic Letters, , vol. 14, # 9 p. 2262 - 2265
反应条件
dicyclohexyl(2′,6′-dimethoxybiphenyl-2-yl)phosphine; palladium diacetate; potassium phosphate in tetrahydrofuran; N,N-dimethyl-formamide T=60°C; Suzuki-Miyaura reaction; 2 h;
参考文献
Flaherty, Alice; Trunkfield, Amy; Barton, William
Organic Letters, 2005 , vol. 7, # 22 p. 4975 - 4978
反应条件
dicyclohexyl(2′,6′-dimethoxybiphenyl-2-yl)phosphine; palladium diacetate; potassium phosphate in tetrahydrofuran; N,N-dimethyl-formamide T=60°C; Suzuki-Miyaura reaction; 1 h;
参考文献
Flaherty, Alice; Trunkfield, Amy; Barton, William
Organic Letters, 2005 , vol. 7, # 22 p. 4975 - 4978
反应条件
potassium phosphate; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran; water; N,N-dimethyl-formamide T=60°C; Suzuki-Miyaura reaction; 1 h;
参考文献
Flaherty, Alice; Trunkfield, Amy; Barton, William
Organic Letters, 2005 , vol. 7, # 22 p. 4975 - 4978
反应条件
1: With n-butyllithium in tetrahydrofuran; diethyl ether; hexane T=-90 - 20°C; Inert atmosphere; 2: With water in tetrahydrofuran; diethyl ether; hexane 2 h; Reflux;
参考文献
Antczak, Monika I.; Montchamp, Jean-Luc
Organic Letters, 2008 , vol. 10, # 5 p. 977 - 980
反应条件
di-tert-butyl peroxide; copper diacetate in toluene T=100°C; 24 h; Sealed tubeInert atmosphere;
参考文献
Sueki, Shunsuke; Kuninobu, Yoichiro
Organic Letters, 2013 , vol. 15, # 7 p. 1544 - 1547
反应条件
dicyclohexyl(2′,6′-dimethoxybiphenyl-2-yl)phosphine; palladium diacetate; potassium phosphate in tetrahydrofuran; N,N-dimethyl-formamide T=60°C; Suzuki-Miyaura reaction; 2 h;
参考文献
Flaherty, Alice; Trunkfield, Amy; Barton, William
Organic Letters, 2005 , vol. 7, # 22 p. 4975 - 4978
