2-(3,4,5-三羟基苯氧基)苯-1,3,5-三醇合成路线 （共 8 条）
反应条件
boron tribromide in dichloromethane
参考文献
Glombitza, Karl-Werner; Woelwer-Rieck, Ursula
Liebigs Annalen der Chemie, 1988 , p. 261 - 266
反应条件
hydrogenchloride in methanol
参考文献
Sattler; Glombitza
Archiv der Pharmazie, 1975 , vol. 308, # 11 p. 813 - 818
反应条件
1: Cu2O, collidine
2: (i) BBr3, CH2Cl2, (ii) /BRN= 385737/, Py
3: HCl / methanol
View Scheme
参考文献
Sattler; Glombitza
Archiv der Pharmazie, 1975 , vol. 308, # 11 p. 813 - 818
反应条件
1: Cu2O, collidine
2: (i) BBr3, CH2Cl2, (ii) /BRN= 385737/, Py
3: HCl / methanol
View Scheme
参考文献
Sattler; Glombitza
Archiv der Pharmazie, 1975 , vol. 308, # 11 p. 813 - 818
反应条件
1: 50 percent / 3-chloroperoxybenzoic acid / CH2Cl2 / 3 h / 20 °C
2: 41 percent / CuO / various solvent(s) / 63 h / Heating
3: 58 percent / boron tribromide / CH2Cl2 / 1 h / -80 °C
View Scheme
参考文献
Paizs, Csaba; Bartlewski-Hof, Ulrike; Retey, Janos
Chemistry - A European Journal, 2007 , vol. 13, # 10 p. 2805 - 2811
反应条件
1: 41 percent / CuO / various solvent(s) / 63 h / Heating
2: 58 percent / boron tribromide / CH2Cl2 / 1 h / -80 °C
View Scheme
参考文献
Paizs, Csaba; Bartlewski-Hof, Ulrike; Retey, Janos
Chemistry - A European Journal, 2007 , vol. 13, # 10 p. 2805 - 2811
反应条件
1: 41 percent / CuO / various solvent(s) / 63 h / Heating
2: 58 percent / boron tribromide / CH2Cl2 / 1 h / -80 °C
View Scheme
参考文献
Paizs, Csaba; Bartlewski-Hof, Ulrike; Retey, Janos
Chemistry - A European Journal, 2007 , vol. 13, # 10 p. 2805 - 2811
反应条件
1.1: aq. HBr; NaNO2 / 0.5 h
1.2: 75 percent / CuBr / H2O / 20 - 100 °C
2.1: 41 percent / CuO / various solvent(s) / 63 h / Heating
3.1: 58 percent / boron tribromide / CH2Cl2 / 1 h / -80 °C
View Scheme
参考文献
Paizs, Csaba; Bartlewski-Hof, Ulrike; Retey, Janos
Chemistry - A European Journal, 2007 , vol. 13, # 10 p. 2805 - 2811
