5-乙酰基-2-甲氧基苯甲醛合成路线 （共 11 条）
参考文献
Gray; Bonner
Journal of the American Chemical Society, 1948 , vol. 70, p. 1249,1250
反应条件
1: aqueous hydrochloric acid / Hydrogenation.Diazotierung mit einer aus Natriumcyanid, Kupfer(I)-chlorid und Wasser hergestellten Loesung
2: HCl; SnCl2; diethyl ether / Einleiten von HCl in das Reaktionsgemisch und Erwaermen des Reaktionsprodukts mit Wasser
View Scheme
参考文献
Gray; Bonner
Journal of the American Chemical Society, 1948 , vol. 70, p. 1249,1250
反应条件
hydrogenchloride; diethyl ether; tin(ll) chloride
Einleiten von HCl in das Reaktionsgemisch und Erwaermen des Reaktionsprodukts mit Wasser;
参考文献
Gray; Bonner
Journal of the American Chemical Society, 1948 , vol. 70, p. 1249,1250
反应条件
hydrogenchloride in tetrahydrofuran
Ambient temperature; Yield given;
参考文献
Laali, Kenneth K.; Koser, Gerald F.; Subramanyam, Sundar; Forsyth, David A.
Journal of Organic Chemistry, 1993 , vol. 58, # 6 p. 1385 - 1392
反应条件
1: 68 percent / AlCl3 / CH2Cl2
2: p-TsOH*H2O / benzene / Heating
3: 1) n-BuLi / 1) hexanes, THF, dry ice bath, 10-15 min, 2) 0 deg C, 1 h, 3) r.t., 1.28 h
4: 2.5 N HCl / tetrahydrofuran / Ambient temperature
View Scheme
参考文献
Laali, Kenneth K.; Koser, Gerald F.; Subramanyam, Sundar; Forsyth, David A.
Journal of Organic Chemistry, 1993 , vol. 58, # 6 p. 1385 - 1392
反应条件
1: p-TsOH*H2O / benzene / Heating
2: 1) n-BuLi / 1) hexanes, THF, dry ice bath, 10-15 min, 2) 0 deg C, 1 h, 3) r.t., 1.28 h
3: 2.5 N HCl / tetrahydrofuran / Ambient temperature
View Scheme
参考文献
Laali, Kenneth K.; Koser, Gerald F.; Subramanyam, Sundar; Forsyth, David A.
Journal of Organic Chemistry, 1993 , vol. 58, # 6 p. 1385 - 1392
反应条件
1: 1) n-BuLi / 1) hexanes, THF, dry ice bath, 10-15 min, 2) 0 deg C, 1 h, 3) r.t., 1.28 h
2: 2.5 N HCl / tetrahydrofuran / Ambient temperature
View Scheme
参考文献
Laali, Kenneth K.; Koser, Gerald F.; Subramanyam, Sundar; Forsyth, David A.
Journal of Organic Chemistry, 1993 , vol. 58, # 6 p. 1385 - 1392
反应条件
ethanol; 1,3,5,7-tetra-azatricyclo[5.1.1.13,5]decane
参考文献
Angyal et al.
Journal of the Chemical Society, 1950 , p. 2141,2142,2144
反应条件
1: water; HCl / 45 °C
2: hexamethylenetetramine; aqueous ethanol
View Scheme
参考文献
Angyal et al.
Journal of the Chemical Society, 1950 , p. 2141,2142,2144
参考文献
Gray; Bonner
Journal of the American Chemical Society, 1948 , vol. 70, p. 1249,1250
