7,7-二氯二环[3.2.0]庚-2-烯-6-酮合成路线 (共 14 条)
反应条件
triethylamine in pentane 4 h; Heating;
参考文献
Baya, Mounir; Soulounganga, Patrice; Gelhaye, Eric; Grardin, Philippe
Pest Management Science, 2001 , vol. 57, # 9 p. 833 - 838
反应条件
zinc in diethyl ether T=0°C; 1 h;
参考文献
Ussing, Bryson R.; Hang, Chao; Singleton, Daniel A.
Journal of the American Chemical Society, 2006 , vol. 128, # 23 p. 7594 - 7607
反应条件
triethylamine in hexane T=26 - 30°C; 9 h;
参考文献
Depres; Greene; Crabbe
Tetrahedron, 1981 , vol. 37, # 3 p. 621 - 628
反应条件
sulfuric acid in methanol 18 h; Ambient temperature;
参考文献
Fleming, Ian; Williams, Richard Vaughan
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 684 - 688
参考文献
Tetrahedron Letters, , p. 3489 - 3490
J, Organometal. Chem., , vol. 42, p. 117 - 121
参考文献
Journal of Organometallic Chemistry, , vol. 42, p. 117 - 121
反应条件
1: 70 percent / Zn/Cu / acetic acid 2: baker's yeast; sucrose / H2O / 72 h / Enzymatic reaction 3: CrO3; H2SO4 4: 75 percent / MCPBA; NaHCO3 / CH2Cl2 / 25 °C View Scheme
参考文献
Fairlamb, Ian J.S.; Dickinson, Julia M.; O'Connor, Rachael; Higson, Seamus; Grieveson, Lynsey; Marin, Veronica
Bioorganic and Medicinal Chemistry, 2002 , vol. 10, # 8 p. 2641 - 2656
反应条件
1: 70 percent / Zn/Cu / acetic acid 2: baker's yeast; sucrose / H2O / 72 h / Enzymatic reaction 3: CrO3; H2SO4 4: 75 percent / MCPBA; NaHCO3 / CH2Cl2 / 25 °C View Scheme
参考文献
Fairlamb, Ian J.S.; Dickinson, Julia M.; O'Connor, Rachael; Higson, Seamus; Grieveson, Lynsey; Marin, Veronica
Bioorganic and Medicinal Chemistry, 2002 , vol. 10, # 8 p. 2641 - 2656
反应条件
sodium hydroxide; acetic acid T=130°C; Rearrangement; 7 h;
参考文献
Chen, Arh-Hwang
Journal of the Chinese Chemical Society, 1999 , vol. 46, # 1 p. 35 - 39
反应条件
1: Zn, HOAc / 80 °C 2: L-Selectride / tetrahydrofuran / -80 °C 3: 87 percent / pyridine, DMAP / CH2Cl2 View Scheme
参考文献
Klempier, Norbert; Geymayer, Paul; Stadler, Peter; Faber, Kurt; Griengl, Herfried
Tetrahedron: Asymmetry, 1990 , vol. 1, # 2 p. 111 - 118