1-羟基-5-甲氧基-9,10-蒽醌合成路线 （共 15 条）
反应条件
sodium hydroxide; sodium dithionite in methanol; water T=20°C; 3 h;
参考文献
Krohn; Baltus
Tetrahedron, 1988 , vol. 44, # 1 p. 49 - 54
反应条件
aluminium trichloride in dichloromethane
T=0°C; 0.5 h;
参考文献
Laugraud; Guingant; Chassagnard; d'Angelo
Journal of Organic Chemistry, 1988 , vol. 53, # 7 p. 1557-1560
反应条件
sodium hydroxide in methanol
参考文献
Bayer Aktiengesellschaft
Patent: US3971812 A1, 1976 ;
反应条件
boron trifluoride diethyl etherate in 1,2-dichloro-benzene
2 h; Heating;
参考文献
Beauregard, Daniel A.; Cambie, Richard C.; Dansted, Paul C.; Rutledge, Peter S.; Woodgate, Paul D.
Australian Journal of Chemistry, 1995 , vol. 48, # 3 p. 669 - 676
反应条件
chromium(VI) oxide; boric acid in water; acetic acid
Heating;
参考文献
Baldwin, Jack E.; Rajeckas, Algis J.
Tetrahedron, 1982 , vol. 38, # 20 p. 3079 - 3084
反应条件
1: 75 percent / KOH / methanol; tetrahydrofuran / 2.5 h / Ambient temperature
2: 100 percent / 12 N aq. HCl / ethanol / 0.25 h / Heating
3: 91 percent / Ag2O / CH2Cl2 / 15 h
4: 79 percent / CH2Cl2 / 78 h / Heating
5: 90 percent / Jones reagent / acetone / 0 °C
6: 90 percent / AlCl3 / CH2Cl2 / 0.5 h / 0 °C
View Scheme
参考文献
Laugraud; Guingant; Chassagnard; d'Angelo
Journal of Organic Chemistry, 1988 , vol. 53, # 7 p. 1557-1560
反应条件
1: 79 percent / CH2Cl2 / 78 h / Heating
2: 90 percent / Jones reagent / acetone / 0 °C
3: 90 percent / AlCl3 / CH2Cl2 / 0.5 h / 0 °C
View Scheme
参考文献
Laugraud; Guingant; Chassagnard; d'Angelo
Journal of Organic Chemistry, 1988 , vol. 53, # 7 p. 1557-1560
反应条件
1: 91 percent / Ag2O / CH2Cl2 / 15 h
2: 79 percent / CH2Cl2 / 78 h / Heating
3: 90 percent / Jones reagent / acetone / 0 °C
4: 90 percent / AlCl3 / CH2Cl2 / 0.5 h / 0 °C
View Scheme
参考文献
Laugraud; Guingant; Chassagnard; d'Angelo
Journal of Organic Chemistry, 1988 , vol. 53, # 7 p. 1557-1560
反应条件
1: 90 percent / Jones reagent / acetone / 0 °C
2: 90 percent / AlCl3 / CH2Cl2 / 0.5 h / 0 °C
View Scheme
参考文献
Laugraud; Guingant; Chassagnard; d'Angelo
Journal of Organic Chemistry, 1988 , vol. 53, # 7 p. 1557-1560
反应条件
1: Na2CO3 / various solvent(s)
2: 1) BF3*Et2O, 2) MeOH / 1) o-dichlorobenzene, reflux, 2) 50-60 degC, 10 min
View Scheme
参考文献
Preston, Peter N.; Winwick, Thomas; Morley, John O.
Journal of the Chemical Society, Chemical Communications, 1983 , # 2 p. 89 - 90
