2,3-二甲基-5-亚甲基-2-环戊烯-1-酮合成路线 （共 64 条）
反应条件
1: 1.) lithium diisopropylamide (LDA) / 1.) THF, from -70 deg C to 0 deg C
2: 1.) lithium diisopropylamide (LDA) / 1.) THF, from -70 deg C to RT
3: 30percent H2O2 / acetone / 0 °C
View Scheme
参考文献
Mathew, Jacob
Journal of the Chemical Society, Chemical Communications, 1990 , # 18 p. 1264 - 1266
反应条件
1: 1.) lithium diisopropylamide (LDA) / 1.) THF, from -70 deg C to RT
2: 30percent H2O2 / acetone / 0 °C
View Scheme
参考文献
Mathew, Jacob
Journal of the Chemical Society, Chemical Communications, 1990 , # 18 p. 1264 - 1266
反应条件
bromine; zinc
1.) CCl4, 23 deg C, 10 h, 2.) Et2O, acetic acid, from 10 to 23 deg C, 40 min; Yield given. Multistep reaction;
参考文献
Welch; Assercq; Loh; Glase
Journal of Organic Chemistry, 1987 , vol. 52, # 8 p. 1440 - 1450
反应条件
sodium periodate; sodium hydrogencarbonate
1.) acetone, H2O, room temp., 24 h, 2.) hexane, ether, reflux, 4 h; Yield given. Multistep reaction;
参考文献
Mikolajzyk; Balczewski
Synthesis, 1984 , vol. NO. 8, p. 691 - 694
