2,3-二甲基-5-亚甲基-2-环戊烯-1-酮合成路线 （共 64 条）
反应条件
sodium tetrahydroborate in ethanol
T=0°C; 3 h; Yield given;
参考文献
Tonari Machiya Ichimoto; Ueda
Agricultural and Biological Chemistry, 1981 , vol. 45, # 1 p. 295 - 300
反应条件
tetrakis(triphenylphosphine) palladium(0); triethylamine in tetrahydrofuran
T=60°C; P=760 Torr; 24 h;
参考文献
Negishi; Ma; Amanfu; Coperet; Miller; Tour
Journal of the American Chemical Society, 1996 , vol. 118, # 25 p. 5919 - 5931
反应条件
tetrakis(triphenylphosphine) palladium(0); triethylamine in tetrahydrofuran
T=60°C; P=836 Torr; 24 h;
参考文献
Negishi,E.I.; Miller,J.A.
Journal of the American Chemical Society, 1983 , vol. 105, p. 6761
反应条件
2,6-dimethylpyridine; trifluoroacetic anhydride; iron(III) chloride in dichloromethane
T=-20°C;
参考文献
Tius, Marcus A.; Astrab, Donald P.; Fauq, Abdul H.; Ousset, Jean-Bernard; Trehan, Sanjay
Journal of the American Chemical Society, 1986 , vol. 108, # 12 p. 3438 - 3442
反应条件
2,6-dimethylpyridine; trifluoroacetic anhydride in dichloromethane
T=-20°C;
参考文献
Tius, Marcus A.; Astrab, Donald P.; Fauq, Abdul H.; Ousset, Jean-Bernard; Trehan, Sanjay
Journal of the American Chemical Society, 1986 , vol. 108, # 12 p. 3438 - 3442
反应条件
in neat (no solvent)
T=110°C; P=0.02 - 0.05 Torr;
参考文献
Pohmakotr, Manat; Chancharunee, Sirirat
Tetrahedron Letters, 1984 , vol. 25, # 37 p. 4141 - 4144
反应条件
potassium carbonate in ethanol
参考文献
Mikolajczyk, Marian; Zatorski, Andrzej
Journal of Organic Chemistry, 1991 , vol. 56, # 3 p. 1217 - 1223
反应条件
potassium carbonate in ethanol; water
8 h; Ambient temperature;
参考文献
Mikolajczyk, Marian; Zatorski, Andrzej
Journal of Organic Chemistry, 1991 , vol. 56, # 3 p. 1217 - 1223
反应条件
pyridine; lead(IV) acetate; copper diacetate in benzene
T=80°C; 2 h;
参考文献
Camps; Coll; Moreto; Torras
Tetrahedron Letters, 1985 , vol. 26, # 51 p. 6397 - 6398
反应条件
dihydrogen peroxide in dichloromethane
0.5 h; ice-bath temperature;
参考文献
Mathew, Jacob
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1991 , # 8 p. 2039 - 2043
