4-(9-咔唑)基-4苯胺合成路线 （共 13 条）
反应条件
1.1: hydrogenchloride; sodium nitrite / water / 0.5 h / 0 °C
1.2: 0.5 h / 0 - 20 °C
2.1: boron trifluoride diethyl etherate / acetonitrile / 0.5 h / 0 - 20 °C / |Inert atmosphere
View Scheme
参考文献
Zhu, Chuan; Yamane, Motoki
Organic Letters, 2012 , vol. 14, # 17 p. 4560 - 4563
反应条件
tin(ll) chloride in methanol
4 h; Heating;
参考文献
Wang, Hui; Ryu, Jeong-Tak; Han, Yoon Soo; Kim, Dae-Hwan; Choi, Byeong Dae; Kwon, Younghwan
Molecular Crystals and Liquid Crystals, 2007 , vol. 463, # 1 p. 3 - 13
反应条件
copper(I) oxide in diphenylether
T=190°C; Ullmann Reaction; 24 h;
参考文献
AGENCY FOR SCIENCE, TECHNOLOGY AND RESEARCH
Patent: WO2008/69756 A1, 2008 ;
Location in patent: Page/Page column 23; Sheet 2/7 ;
反应条件
sulfuric acid in tetrahydrofuran; methanol; water
2 h; Heating;
参考文献
Kimoto, Atsushi; Cho, Jun-Sang; Higuchi, Masayoshi; Yamamoto, Kimihisa
Macromolecules, 2004 , vol. 37, # 15 p. 5531 - 5537
反应条件
1: 98 percent / K3PO4; trans-1,2-cyclohexanediamine / CuI / dioxane / 24 h / Heating
2: 98 percent / SnCl2 / methanol / 4 h / Heating
View Scheme
参考文献
Wang, Hui; Ryu, Jeong-Tak; Han, Yoon Soo; Kim, Dae-Hwan; Choi, Byeong Dae; Kwon, Younghwan
Molecular Crystals and Liquid Crystals, 2007 , vol. 463, # 1 p. 3 - 13
反应条件
1: 98 percent / caesium fluoride / dimethylsulfoxide / 15 h / 150 °C
2: hydrazine monohydrate / Pd/C / ethanol / 9 h / Heating
View Scheme
参考文献
Liou, Guey-Sheng; Hsiao, Sheng-Huei; Chen, Hwei-Wen
Journal of Materials Chemistry, 2006 , vol. 16, # 19 p. 1831 - 1842
反应条件
potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene in toluene
T=100°C; 5 h; Inert atmosphere;
参考文献
Hung, Tran Quang; Thang, Ngo Ngoc; Hoang, Do Huy; Dang, Tuan Thanh; Villinger, Alexander; Langer, Peter
Organic and Biomolecular Chemistry, 2014 , vol. 12, # 16 p. 2596 - 2605
反应条件
1.1: KOH / 350 °C
1.2: 72 percent / 48 h / 55 °C
2.1: 95 percent / SnCl2*2H2O / ethanol / 6 h / Heating
View Scheme
参考文献
Chen, Yen-Chun; Huang, Guo-Sheng; Hsiao, Chung-Chin; Chen, Show-An
Journal of the American Chemical Society, 2006 , vol. 128, # 26 p. 8549 - 8558
反应条件
1: 98 percent / K3PO4; trans-1,2-cyclohexanediamine / CuI / dioxane / 24 h / Heating
2: 98 percent / SnCl2 / methanol / 4 h / Heating
View Scheme
参考文献
Wang, Hui; Ryu, Jeong-Tak; Han, Yoon Soo; Kim, Dae-Hwan; Choi, Byeong Dae; Kwon, Younghwan
Molecular Crystals and Liquid Crystals, 2007 , vol. 463, # 1 p. 3 - 13
反应条件
1: 77 percent / Cu2O / N,N-dimethyl-acetamide / 24 h / 160 °C
2: 99 percent / H2SO4 / H2O; tetrahydrofuran; methanol / 2 h / Heating
View Scheme
参考文献
Kimoto, Atsushi; Cho, Jun-Sang; Higuchi, Masayoshi; Yamamoto, Kimihisa
Macromolecules, 2004 , vol. 37, # 15 p. 5531 - 5537
