1: With potassium tert-butylate; silver(I) acetate; triphenylphosphine in tetrahydrofuran T=70°C; P=15201 Torr; 16 h; Inert atmosphereAutoclave; 2: With hydrogenchloride in tetrahydrofuran; water Inert atmosphere;
1: thien-2-yl bromide With magnesium in tetrahydrofuran 0.75 h; Inert atmosphereReflux; 2: carbon dioxide in tetrahydrofuran T=-78 - 20°C;
参考文献
Van De Kruijs, Bastiaan H. P.; Dressen, Mark H. C. L.; Meuldijk, Jan; Vekemans, Jef A. J. M.; Hulshof, Lumbertus A.
Organic and Biomolecular Chemistry, 2010 , vol. 8, # 7 p. 1688 - 1694
1: With palladium diacetate; tri-cyclo-hexyl-phosphine in tetrahydrofuran T=0°C; P=760.051 Torr; Inert atmosphere; 2: With hydrogenchloride in tetrahydrofuran; water; ethyl acetate
参考文献
Yeung, Charles S.; Dong, Vy M.
Journal of the American Chemical Society, 2008 , vol. 130, # 25 p. 7826 - 7827
