2,6-二甲基-2,5-环己二烯-1,4-二酮合成路线 (共 148 条)
反应条件
1: 41 percent / Pb(OAc)4 / ethyl acetate / 45 °C 2: 76 percent / H2O / acetone / 6 h / Heating View Scheme
参考文献
Fernando; Calder; Ham
Journal of Medicinal Chemistry, 1980 , vol. 23, # 11 p. 1153 - 1158
反应条件
1: sodium dithionite; aqueous ethanol 2: aqueous solution; Fe2(SO4)3; steam View Scheme
参考文献
Smith; Irwin
Journal of the American Chemical Society, 1941 , vol. 63, p. 1036,1040
反应条件
silver(l) oxide in acetic acid T=10 - 15°C; 0.5 h;
参考文献
Avdeenko; Konovalova; Sergeeva; Zubatyuk; Palamarchuk; Shishkin
Russian Journal of Organic Chemistry, 2008 , vol. 44, # 12 p. 1765 - 1772
反应条件
nitric acid in acetic acid T=20°C; 0.166667 h; Further byproducts given;
参考文献
Hartshorn, Michael P.; Readman, Jennifer M.; Robinson, Ward T.; Vaughan, John; Whyte, Andrew R.
Australian Journal of Chemistry, 1985 , vol. 38, # 11 p. 1693 - 1704
反应条件
{Ru(IV)(2,2'-bipyridine)2(pyridine)O}(2+) in acetonitrile-D3 T=25°C; MechanismProduct distribution;
参考文献
Seok, Won K.; Meyer, Thomas J.
Journal of the American Chemical Society, 1988 , vol. 110, # 22 p. 7358 - 7367
反应条件
K10 montmorillonite; water; dihydrogen peroxide in tetrachloromethane T=22°C; Oxidation; 2 h;
参考文献
Bushmelev; Genaev; Shubin
Russian Journal of Organic Chemistry, 1999 , vol. 35, # 1 p. 62 - 66
反应条件
1: 80 percent / m-CPBA / CH2Cl2 / 2 h / -50 - -30 °C 2: 1.) TFAA, allyltrimethylsilane, 2.) NaHCO3 / 1.) CH2Cl2, 0 deg C, 15 min, 2.) MeOH, H2O, 1 h View Scheme
参考文献
Akai, Shuji; Takeda, Yoshifumi; Iio, Kiyosei; Takahashi, Kenji; Fukuda, Nobuhisa; Kita, Yasuyuki
Journal of Organic Chemistry, 1997 , vol. 62, # 16 p. 5526 - 5536
反应条件
1: 1.) NaBH4, 2.) 3 N HCl / 1.) 10percent Pd-C / 1.) H2O, MeOH, rt, 30 min 2: aq. NaNO2, aq. H2SO4 / 0.33 h / 20 °C View Scheme
参考文献
Bucher, Goetz; Sander, Wolfram
Journal of Organic Chemistry, 1992 , vol. 57, # 5 p. 1346 - 1351
反应条件
cerium(IV) sulphate; sulfuric acid in water T=90°C; 2 h; activation energy, mechanism; other times, other temperatures; KineticsMechanismRate constant;
参考文献
Abdelhedi, R.; Bouguerra, M. L.
Bulletin de la Societe Chimique de France, 1991 , # 6 p. 914 - 918
反应条件
K10 montmorillonite; water; dihydrogen peroxide in tetrachloromethane T=22°C; Oxidation; 2 h;
参考文献
Bushmelev; Genaev; Shubin
Russian Journal of Organic Chemistry, 1999 , vol. 35, # 1 p. 62 - 66