2,6-二甲基-2,5-环己二烯-1,4-二酮合成路线 （共 148 条）
反应条件
[bis(acetoxy)iodo]benzene T=20°C; Oxidation; 1 h; Title compound not separated from byproducts;
参考文献
Camps, Pelayo; Gonzalez, Albert; Munoz-Torrero, Diego; Simon, Montserrat; Zuniga, Adriana; Martins, Miriam A.; Font-Bardia, Merce; Solans, Xavier
Tetrahedron, 2000 , vol. 56, # 41 p. 8141 - 8151
反应条件
cerium(IV) chlorate; 4-amino-phenol in perchloric acid 2 h;
参考文献
Domagala; Dziegiec
Monatshefte fur Chemie, 1997 , vol. 128, # 8-9 p. 749 - 757
反应条件
nitric acid; HNO2 T=0°C; 1 h;
参考文献
Helsby, Paul; Ridd, John H.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , p. 311 - 316
反应条件
nitric acid; sodium nitrite in tetrachloromethane Ambient temperature;
参考文献
Bozell, Joseph J.; Hoberg, John O.; Dimmel, Donald R.
Tetrahedron Letters, 1998 , vol. 39, # 16 p. 2261 - 2264
反应条件
K10 montmorillonite; water; dihydrogen peroxide in tetrachloromethane T=22°C; Oxidation; 2 h;
参考文献
Bushmelev; Genaev; Shubin
Russian Journal of Organic Chemistry, 1999 , vol. 35, # 1 p. 62 - 66
反应条件
1: 52 percent / tetrahydrofuran; diethyl ether / 4 h / -50 °C 2: 80 percent / m-CPBA / CH2Cl2 / 2 h / -50 - -30 °C 3: 1.) TFAA, allyltrimethylsilane, 2.) NaHCO3 / 1.) CH2Cl2, 0 deg C, 15 min, 2.) MeOH, H2O, 1 h View Scheme
参考文献
Akai, Shuji; Takeda, Yoshifumi; Iio, Kiyosei; Takahashi, Kenji; Fukuda, Nobuhisa; Kita, Yasuyuki
Journal of Organic Chemistry, 1997 , vol. 62, # 16 p. 5526 - 5536
反应条件
1: 70 percent / HNO3, H2SO4 / 1 h / Ambient temperature 2: 70 percent / H2 / Raney-Ni / ethanol / 1 h 3: 31 percent / Na2Cr2O7*2H2O, 2N aq.H2SO4 / 48 h View Scheme
参考文献
Knorr, Rudolf; Hintermeyer-Hilpert, Monika; Mehlstaeubl, Johann; Hoang, Thi Phung; Neuner, Brigitte; Boehrer, Petra
Chemische Berichte, 1993 , vol. 126, # 1 p. 211 - 216
反应条件
1: 70 percent / H2 / Raney-Ni / ethanol / 1 h 2: 31 percent / Na2Cr2O7*2H2O, 2N aq.H2SO4 / 48 h View Scheme
参考文献
Knorr, Rudolf; Hintermeyer-Hilpert, Monika; Mehlstaeubl, Johann; Hoang, Thi Phung; Neuner, Brigitte; Boehrer, Petra
Chemische Berichte, 1993 , vol. 126, # 1 p. 211 - 216
反应条件
1: 69 percent / PtO2, H2 / acetic acid / 2 h / Ambient temperature 2: 65 percent / Pb(OAc)4 / ethyl acetate / Ambient temperature 3: 41 percent / H2O / acetone / 5 h / Heating View Scheme
参考文献
Fernando; Calder; Ham
Journal of Medicinal Chemistry, 1980 , vol. 23, # 11 p. 1153 - 1158
反应条件
1: 65 percent / Pb(OAc)4 / ethyl acetate / Ambient temperature 2: 41 percent / H2O / acetone / 5 h / Heating View Scheme
参考文献
Fernando; Calder; Ham
Journal of Medicinal Chemistry, 1980 , vol. 23, # 11 p. 1153 - 1158
