2,6-二甲基-2,5-环己二烯-1,4-二酮合成路线 （共 148 条）
反应条件
1: 62 percent / 48percent HBr / acetic acid / 3 h / Heating 2: 1.) NaBH4, 2.) 3 N HCl / 1.) 10percent Pd-C / 1.) H2O, MeOH, rt, 30 min 3: aq. NaNO2, aq. H2SO4 / 0.33 h / 20 °C View Scheme
参考文献
Bucher, Goetz; Sander, Wolfram
Journal of Organic Chemistry, 1992 , vol. 57, # 5 p. 1346 - 1351
反应条件
Na2B4O7; 3,5-Dichlorobenzoquinone N-chloroimine in acetonitrile T=25°C; 0.333333 h; Title compound not separated from byproducts;
参考文献
Pallagi, Istvan; Toro, Andras; Farkas, Oedoen
Journal of Organic Chemistry, 1994 , vol. 59, # 22 p. 6543 - 6557
参考文献
Fernando; Calder; Ham
Journal of Medicinal Chemistry, 1980 , vol. 23, # 11 p. 1153 - 1158
反应条件
2,6-di-tert-butyl-phenol; manganese triacetate; acetic anhydride in acetic acid T=100°C; 0.166667 h; Further byproducts given;
参考文献
Nishino, Hiroshi; Nobuyuki, Itoh; Nagashima, Makiko; Kurosawa, Kazu
Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 2 p. 620 - 622
反应条件
nitrogen(IV) oxide in chloroform-d1 T=-60°C;
参考文献
Fischer, Alfred; Mathivanan, N.
Tetrahedron Letters, 1988 , vol. 29, # 16 p. 1869 - 1872
反应条件
Na2B4O7 in acetonitrile T=25°C; 0.333333 h; Title compound not separated from byproducts;
参考文献
Pallagi, Istvan; Toro, Andras; Farkas, Oedoen
Journal of Organic Chemistry, 1994 , vol. 59, # 22 p. 6543 - 6557
反应条件
H6PMo9V3O40 in benzene T=70°C; 1 h;
参考文献
Titova, T. F.; Mateev, K. I.; Zhizhina, E. G.; Krysin, A. P.
Journal of Organic Chemistry USSR (English Translation), 1991 , vol. 27, # 6.2 p. 1153 - 1156
Zhurnal Organicheskoi Khimii, 1991 , vol. 27, # 6 p. 1321 - 1325
反应条件
[bis(acetoxy)iodo]benzene in hexane; ethylene glycol 0 deg C; 0 deg C to RT, 2 h;
参考文献
Rose, Patricia A.; Lei, Bo; Shaw, Angela C.; Walker-Simmons; Napper, Scott; Quail, J. Wilson; Abrams, Suzanne R.
Canadian Journal of Chemistry, 1996 , vol. 74, # 10 p. 1836 - 1843
反应条件
oxygen; horseradish peroxidase Oxidation; pH=7; electrolysis after 8 F;
参考文献
Pletcher, Derek
Acta Chemica Scandinavica, 1999 , vol. 53, # 10 p. 745 - 750
反应条件
perchloric acid; lead dioxide in acetone Oxidation; 0.25 h;
参考文献
Omura, Kanji
Tetrahedron Letters, 2000 , vol. 41, # 5 p. 685 - 689
