1,2,3,5-四甲基苯合成路线 （共 148 条）
反应条件
1: LiAlH4; diethyl ether 2: hydrogen; CO; benzene / 190 °C / Reagens 4: Octacarbonyldikobalt; Reagens 5: CoCO3 View Scheme
参考文献
Wender et al.
Journal of the American Chemical Society, 1952 , vol. 74, p. 4079,4082
反应条件
1: LiAlH4; diethyl ether 2: hydrogen; CO; benzene / 190 °C / Reagens 4: Octacarbonyldikobalt; Reagens 5: CoCO3 View Scheme
参考文献
Wender et al.
Journal of the American Chemical Society, 1952 , vol. 74, p. 4079,4082
反应条件
acetic anhydride; aluminium trichloride T=35°C; 30 h; Further byproducts given;
参考文献
Andreou, Andreas D.; Bulbulian, Roger V.; Gore, Peter H.; Morris, Donald F. C.; Short, Eric L.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1981 , p. 830 - 837
反应条件
anhydrous methyl chloride; oxygen; 1,3,5-trimethyl-benzene in benzene T=120°C; Irradiationsev. reagents; Product distributionMechanism;
参考文献
Attina, Marina; Cacace, Fulvio; Petris, Giulia de; Fornarini, Simonetta; Giacomello, Pierluigi
Journal of the American Chemical Society, 1985 , vol. 107, p. 2297 - 2302
反应条件
hydrogen fluoride; SbF5 T=25°C; Rate constant;
参考文献
Nightingale; Wadsworth
Journal of the American Chemical Society, 1941 , vol. 63, p. 3514,3516
反应条件
trimethylamine T=40 - 140°C; P=50 - 760 Torr; 24 h; Irradiationpressure and temperature dependence competitive alkylation reactions with the radiolytically formed CH3ClCH3+ ion; Product distributionRate constant;
参考文献
Speranza, Maurizio; Laguzzi, Guiseppe
Journal of the American Chemical Society, 1988 , vol. 110, # 1 p. 30 - 34
反应条件
CH3I in diethyl ether; toluene soln. of CH3I in toluene is added to stirred room-temp. soln. of Cr(C6H2Me3)2(PMe3)2 in diethyl ether, stirring for 3 h; elem. anal.;
参考文献
Hermes, Ann R.; Morris, Robert J.; Girolami, Gregory S.
Organometallics, 1988 , vol. 7, p. 2372 - 2379
反应条件
trifluoroacetic acid 15 h; Heating;
参考文献
Keumi, Takashi; Morita, Toshio; Inui, Yoko; Teshima, Naomi; Kitajima, Hidehiko
Synthesis, 1985 , # 10 p. 979 - 980
反应条件
aluminium trichloride T=80 - 85°C;
参考文献
Jacobsen
Chemische Berichte, 1881 , vol. 14, p. 2629
反应条件
hydrogen fluoride; boron trifluoride
参考文献
Vavon; Bolle; Calin
Bulletin de la Societe Chimique de France, 1939 , vol. <5> 6, p. 1025,1033
