beta,beta,4-三氯苯乙烯合成路线 （共 16 条）
反应条件
1: trichloromethanephosphonic acid diethyl ester With n-butyllithium in tetrahydrofuran
T=-100°C; 0.166667 h; Inert atmosphere;
2: 4-chlorobenzaldehyde in tetrahydrofuran
T=-100 - 20°C; Inert atmosphere;
参考文献
Arthuis, Martin; Lecup, Anne; Roulland, Emmanuel
Chemical Communications, 2010 , vol. 46, # 41 p. 7810 - 7812
反应条件
samarium diiodide in tetrahydrofuran
T=20°C; 0.0833333 h;
参考文献
Li, Jian; Xu, Xiaoliang; Zhang, Yongmin
Tetrahedron Letters, 2003 , vol. 44, # 52 p. 9349 - 9351
反应条件
ethylenediamine; copper(l) chloride in ethanol
T=20°C; 24 h;
参考文献
Korotchenko; Shastin; Nenaidenko; Balenkova
Russian Journal of Organic Chemistry, 2003 , vol. 39, # 4 p. 527 - 531
反应条件
samarium diiodide in tetrahydrofuran
T=20°C; 0.0833333 h;
参考文献
Li, Jian; Xu, Xiaoliang; Zhang, Yongmin
Tetrahedron Letters, 2003 , vol. 44, # 52 p. 9349 - 9351
反应条件
Cu2Cl2; ammonium hydroxide in dimethyl sulfoxide
T=20°C; Oxidation; condensation; 4 h;
参考文献
Shastin; Korotchenko; Nenajdenko; Balenkova
Tetrahedron, 2000 , vol. 56, # 35 p. 6557 - 6563
反应条件
sulfuric acid in dichloromethane
2 h; Ambient temperature;
参考文献
Hosomi, Akira; Inaba, Masahiro; Sakurai, Hideki
Tetrahedron Letters, 1983 , vol. 24, # 43 p. 4727 - 4728
反应条件
ammonium hydroxide; copper(l) chloride in dimethyl sulfoxide
T=20°C; 24 h;
参考文献
Nenaidenko; Korotchenko; Shastin; Tyurin; Balenkova
Russian Journal of Organic Chemistry, 2004 , vol. 40, # 12 p. 1750 - 1756
反应条件
hydrogenchloride; lead(II) bromide; aluminium in methanol
T=50 - 60°C; 7 h;
参考文献
Tanaka, Hideo; Yamashita, Shiro; Yamanoue, Motoi; Torii, Sigeru
Journal of Organic Chemistry, 1989 , vol. 54, # 2 p. 444 - 450
反应条件
tetraethylammonium bromide in acetonitrile
Ambient temperatureelectrosynthesis, carbon-felt cathode, Pt anode(in cyclohexene), 100 mA intensity;
参考文献
Jubault, Philippe; Feasson, Christian; Collignon, Noel
Bulletin de la Societe Chimique de France, 1994 , vol. 131, p. 1001 - 1006
反应条件
1: 4-chlorobenzaldehyde With hydrazine hydrate
2: trichloromonobromomethane With ethylenediamine in ethanol
24 h;
参考文献
Nenajdenko, Valentine G.; Vasil'Kov, Alexander Yu.; Goldberg, Aleksey A.; Muzalevskiy, Vasiliy M.; Naumkin, Alexander V.; Podshibikhin, Vladislav L.; Shastin, Aleksey V.; Balenkova, Elizabeth S.
Mendeleev Communications, 2010 , vol. 20, # 4 p. 200 - 202
