1: 1.) magnesium / 1.) ether, 2.) ice-bath, 4 h
2: 1.) conc. HCl, sodium nitrite, 2.) sodium azide, sodium acetate / 1.) acetic acid, water, below 5 deg C
3: 49 percent / various solvent(s) / 3 h / Heating
4: various solvent(s) / 4 h / Heating
View Scheme
参考文献
Hawkins, David G.; Meth-Cohn, Otto
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , p. 2077 - 2087
1: 1.) magnesium / 1.) ether, 2.) ice-bath, 4 h
2: 1.) conc. HCl, sodium nitrite, 2.) sodium azide, sodium acetate / 1.) acetic acid, water, below 5 deg C
3: 94 percent / various solvent(s) / 3 h / Heating
4: 29 percent / various solvent(s) / 6 h / Heating
View Scheme
参考文献
Hawkins, David G.; Meth-Cohn, Otto
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , p. 2077 - 2087
1.1: ammonia / ethanol / 2 h / |Reflux
2.1: nitric acid / |Heating
3.1: acetic anhydride / 130 °C
3.2: 2 h / |Reflux
View Scheme
参考文献
Akbari, Vikunjana K; Kahar, Ramprasad G; Patel, Keshav C
Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2013 , vol. 52, # 11 p. 1462 - 1467
Saxena, Sushma; Verma, M; Saxena, A K; Gupta, G P; Shanker, K
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1991 , vol. 30, # 4 p. 453 - 456
