1,2,3-三甲基-5-硝基-苯合成路线 (共 6 条)
参考文献
Dollinsky et al.
Journal of the Association of Official Agricultural Chemists, 1959 , vol. 42, p. 709,716
反应条件
tris-(dibenzylideneacetone)dipalladium(0); t-Bu Brett Phos; TDA; sodium nitrite in tert-butyl alcohol
T=130°C; 24 h; regioselective reaction;
参考文献
Fors, Brett P.; Buchwald, Stephen L.
Journal of the American Chemical Society, 2009 , vol. 131, # 36 p. 12898 - 12899
反应条件
silver nitrate; boron trifluoride in acetonitrile
T=25°C; 5 h; competitive nitration benzene, relative rate; Product distribution;
参考文献
Olah, George A.; Fung, Alexander P.; Narang, Subhash C.; Olah, Judith A.
Journal of Organic Chemistry, 1981 , vol. 46, # 17 p. 3533 - 3537
反应条件
TNM; trifluoroacetic acid in dichloromethane
T=20°C; 8 h; Irradiation2.08 M acid; Further byproducts given;
参考文献
Butts, Craig P.; Eberson, Lennart; Hartshorn, Michael P.; Robinson, Ward T.; Timmerman-Vaughan, David J.; Young, Dawson A. W.
Acta Chemica Scandinavica, 1996 , vol. 50, # 1 p. 29 - 47
反应条件
sulfuric acid; dihydrogen peroxide
参考文献
Degani,J. et al.
Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy, 1967 , vol. 23, p. 1351 - 1372
反应条件
Product distribution;
参考文献
Dollinsky et al.
Journal of the Association of Official Agricultural Chemists, 1959 , vol. 42, p. 709,716