4,4’-二氰基二苯乙烯合成路线 （共 18 条）
反应条件
C71H58MoN2O3Si3; manganese (II) chloride in toluene T=20 - 80°C; Inert atmosphereMolecular sieve;
参考文献
Heppekausen, Johannes; Stade, Robert; Kondoh, Azusa; Seidel, Guenter; Goddard, Richard; Fuerstner, Alois
Chemistry - A European Journal, 2012 , vol. 18, # 33 p. 10281 - 10299
反应条件
tetrakis(triphenylphosphine) palladium(0); copper(l) chloride in N,N-dimethyl-formamide T=80°C; sila-Sonogashira reaction; 6 h;
参考文献
Nishihara, Yasushi; Inoue, Eiji; Noyori, Shintaro; Ogawa, Daisuke; Okada, Yoshiaki; Iwasaki, Masayuki; Takagi, Kentaro
Tetrahedron, 2012 , vol. 68, # 24 p. 4869 - 4881
反应条件
tetrakis(triphenylphosphine) palladium(0) in 1,4-dioxane T=100°C; Stille coupling; 2 h; Inert atmosphere;
参考文献
Brown, Amy E.; Eichler, Barrett E.
Tetrahedron Letters, 2011 , vol. 52, # 16 p. 1960 - 1963
反应条件
copper(l) iodide; [1,4-bis-(diphenylphosphine)butane]palladium (II) dichloride; triethylamine; triphenylphosphine T=100°C; 2 h; Inert atmosphere;
参考文献
Berger, Olivier; Kaniti, Archana; van Ba, Christophe Tran; Vial, Henri; Ward, Stephen A.; Biagini, Giancarlo A.; Bray, Patrick G.; O'Neill, Paul M.
ChemMedChem, 2011 , vol. 6, # 11 p. 2094 - 2108
反应条件
dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct; N-ethyl-N,N-diisopropylamine in water; isopropyl alcohol T=100°C; 0.333333 h; Microwave irradiationInert atmosphere;
参考文献
Coltuclu, Vitali; Dadush, Eric; Naravane, Abhijit; Kabalka, George W.
Molecules, 2013 , vol. 18, # 2 p. 1755 - 1761
反应条件
1: 1,2-bis(methylthio)acetylene With palladium diacetate; bis[2-(diphenylphosphino)phenyl] ether in tetrahydrofuran 0.166667 h; Inert atmosphere; 2: p-cyanophenylzinc iodide-lithium chloride complex in tetrahydrofuran T=50°C; 16 h; Inert atmosphere;
参考文献
Melzig, Laurin; Metzger, Albrecht; Knochel, Paul
Chemistry - A European Journal, 2011 , vol. 17, # 10 p. 2948 - 2956
反应条件
potassium hydroxide in dimethyl sulfoxide
参考文献
Vernigor, E. M.; Shalaev, V. K.; Luk'yanets, E. A.
Journal of Organic Chemistry USSR (English Translation), 1981 , vol. 17, # 2 p. 317 - 321
Zhurnal Organicheskoi Khimii, 1981 , vol. 17, # 2 p. 374 - 379
反应条件
tetrakis(triphenylphosphine) palladium(0); copper(l) chloride in N,N-dimethyl-formamide T=80°C; cross-coupling; 12 h;
参考文献
Nishihara, Yasushi; Ikegashira, Kazutaka; Hirabayashi, Kazunori; Ando, Jun-Ichi; Mori, Atsunori; Hiyama, Tamejiro
Journal of Organic Chemistry, 2000 , vol. 65, # 6 p. 1780 - 1787
反应条件
1,3-dimethyl-imidazolidin-2-one; potassium carbonate; triphenylphosphine; copper(l) chloride T=120°C; 12 h;
参考文献
Ogawa, Daisuke; Li, Jing; Suetsugu, Masato; Jiao, Jiao; Iwasaki, Masayuki; Nishihara, Yasushi
Tetrahedron Letters, 2013 , vol. 54, # 6 p. 518 - 521
反应条件
copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); diisopropylamine T=20°C; 15 h; Inert atmosphere;
参考文献
Moreno-Garcia, Pavel; Gulcur, Murat; Manrique, David Zsolt; Pope, Thomas; Hong, Wenjing; Kaliginedi, Veerabhadrarao; Huang, Cancan; Batsanov, Andrei S.; Bryce, Martin R.; Lambert, Colin; Wandlowski, Thomas
Journal of the American Chemical Society, 2013 , vol. 135, # 33 p. 12228 - 12240
