N-亚苄基-4-甲基苯磺酰胺合成路线 （共 129 条）
反应条件
[RhCl(η2:η2-cycloocta-1,5-diene)]2; potassium tert-butylate; triphenylphosphine in tetrahydrofuran T=40°C; 14 h; Molecular sieve; optical yield given as percent de;
参考文献
Ahlsten, Nanna; Martin-Matute, Belen
Advanced Synthesis and Catalysis, 2009 , vol. 351, # 16 p. 2657 - 2666
反应条件
[Cp*Rh(CH3CN)3][SbF6]2 in tert-butyl alcohol T=90°C; 3.5 h; Schlenk techniqueInert atmosphere;
参考文献
Zhang, Xi-Sha; Li, Yang; Li, Hu; Chen, Kang; Lei, Zhi-Quan; Shi, Zhang-Jie
Chemistry - A European Journal, 2012 , vol. 18, # 50 p. 16214 - 16225
反应条件
[RhCl(η2:η2-cycloocta-1,5-diene)]2; potassium tert-butylate; triphenylphosphine in tetrahydrofuran T=40°C; 14 h; Molecular sieve; optical yield given as percent de;
参考文献
Ahlsten, Nanna; Martin-Matute, Belen
Advanced Synthesis and Catalysis, 2009 , vol. 351, # 16 p. 2657 - 2666
反应条件
(η5-C5Ph5)Ru(CO)2Cl; potassium tert-butylate in tetrahydrofuran; toluene T=40°C; Mannich type reaction; 15 h; Inert atmosphereMolecular sieve; optical yield given as percent dediastereoselective reaction;
参考文献
Bartoszewicz, Agnieszka; Jezowska, Martina M.; Laymand, Kevin; Moebus, Juri; Martin-Matute, Belen
European Journal of Inorganic Chemistry, 2012 , # 9 p. 1517 - 1530
反应条件
dimethyl sulfoxide T=20°C; Knoevenagel condensation; 24 h; Inert atmosphereMolecular sieve; optical yield given as percent destereoselective reaction;
参考文献
Chiba, Ryoichi; Oriyama, Takeshi
Chemistry Letters, 2008 , vol. 37, # 12 p. 1218 - 1219
反应条件
1: 91 percent / t-BuOK / 2-methyl-propan-2-ol / 4 h / 50 °C 2: conc. HCl / Heating View Scheme
参考文献
Fan, Renhua; Wang, Weizi; Pu, Dongming; Wu, Jie
Journal of Organic Chemistry, 2007 , vol. 72, # 15 p. 5905 - 5907
反应条件
1: 1.) n-butyllithium / 1.) hexane, THF, -100 deg C, 15 min, 2.) THF, -85 to -100 deg C, 6 h 2: 48 percent / p-TsOH, conc. HCl / methanol; H2O / 96 h / Heating 3: 90 percent / LiAlH4 / tetrahydrofuran / 16 h / Heating 4: 68 percent / Na, liquid ammonia / tetrahydrofuran / 0.75 h / -78 °C View Scheme
参考文献
Wuensch, Bernhard; Nerdinger, Sven
European Journal of Organic Chemistry, 1999 , # 2 p. 503 - 517
反应条件
[Cp*Rh(CH3CN)3][SbF6]2 in tert-butyl alcohol T=90°C; 3.5 h; Schlenk techniqueInert atmosphere;
参考文献
Zhang, Xi-Sha; Li, Yang; Li, Hu; Chen, Kang; Lei, Zhi-Quan; Shi, Zhang-Jie
Chemistry - A European Journal, 2012 , vol. 18, # 50 p. 16214 - 16225
反应条件
[Cp*Rh(CH3CN)3][SbF6]2 in tert-butyl alcohol T=90°C; 16 h; Schlenk techniqueInert atmosphere;
参考文献
Zhang, Xi-Sha; Li, Yang; Li, Hu; Chen, Kang; Lei, Zhi-Quan; Shi, Zhang-Jie
Chemistry - A European Journal, 2012 , vol. 18, # 50 p. 16214 - 16225
反应条件
1: toluene-4-sulfonamide; [Ru2(p-PriC6H4Me)2(μ-Cl)Cl]2; acetic acid; silver hexafluoroantimonate / 1,4-dioxane / 20 h / |Schlenk technique; |Inert atmosphere 2: 1,10-phenanthroline; copper diacetate; oxygen / N,N-dimethyl-formamide / 12 h / 60 °C / 760.05 Torr / |Schlenk technique View Scheme
参考文献
Zhao, Peng; Wang, Fen; Han, Keli; Li, Xingwei
Organic Letters, 2012 , vol. 14, # 21 p. 5506 - 5509,4
