甲氧二甲基(对甲苯基)硅烷合成路线 （共 6 条）
反应条件
[{RuCl2(cymene)}2] T=20°C; 0.0833333 h;
参考文献
Rayment, Elizabeth J.; Summerhill, Nick; Anderson, Edward A.
Journal of Organic Chemistry, 2012 , vol. 77, # 16 p. 7052 - 7060
反应条件
1.1: n-butyllithium / tetrahydrofuran; hexane / 2 h / -78 °C / Inert atmosphere 1.2: -78 - 20 °C / Inert atmosphere 2.1: [{RuCl2(cymene)}2] / 0.08 h / 20 °C View Scheme
参考文献
Rayment, Elizabeth J.; Summerhill, Nick; Anderson, Edward A.
Journal of Organic Chemistry, 2012 , vol. 77, # 16 p. 7052 - 7060
反应条件
hydrogenchloride in 1,4-dioxane T=25°C; 1 h; var. of reagent; Rate constantEquilibrium constant;
参考文献
Kohlheim; Lange; Kelling
Advanced Synthesis and Catalysis, 1996 , vol. 338, # 7 p. 660 - 662
反应条件
T=25°C; Rate constant;
参考文献
Lew, Calvin S. Q.; McClelland, Robert A.
Journal of the American Chemical Society, 1993 , vol. 115, # 24 p. 11516 - 11520
反应条件
magnesium 1.) Et2O, dibromoethane, heating, 1 h; 2.) ether, 40 deg C, 4 h; Yield given. Multistep reaction;
参考文献
Lapkin, I. I.; Mukhina, R. G.; Kirillov, N. F.
J. Gen. Chem. USSR (Engl. Transl.), 1987 , vol. 57, # 1 p. 146 - 151,125 - 129
反应条件
hydrogenchloride in 1,4-dioxane
T=25°C; 1 h; Equilibrium constantRate constant;
参考文献
Kohlheim; Lange; Kelling
Advanced Synthesis and Catalysis, 1996 , vol. 338, # 7 p. 660 - 662
