(S)-A-邻苯二甲酰亚胺丙醛合成路线 （共 8 条）
反应条件
hydrogen; tin(ll) chloride; ((2S,4S)-N-(tert-butoxycarbonyl)-4-(diphenylphosphino)-2-{(diphenylphosphino)methyl}pyrrolidine)PtCl2 in benzene
T=60°C; P=137044 Torr; 46 h; Yield given;
参考文献
Parrinello, Giovanni; Stille, J. K.
Journal of the American Chemical Society, 1987 , vol. 109, # 23 p. 7122 - 7127
反应条件
hydrogen; Pd-BaSO4 in xylene
T=110°C; 10 h;
参考文献
Wyslouch, Aleksandra; Lisowski, Marek; Pedyczak, Artur; Siemion, Ignacy Z.
Tetrahedron: Asymmetry, 1992 , vol. 3, # 11 p. 1401 - 1410
反应条件
sodium hydrogencarbonate; Dess-Martin periodane in dichloromethane
T=20°C; Dess-Martin oxidation; pH=6; 0.5 h;
参考文献
Trifonova, Anna; Andersson, Pher G.
Tetrahedron Asymmetry, 2004 , vol. 15, # 3 p. 445 - 452
反应条件
bis[(S,S,S)-DiazaPhos-SPE]; [rhodium(I)(carbonyl)2(acetylacetonate)]; hydrogen in tetrahydrofuran; toluene
T=40°C; P=7240.26 Torr; 8 h; optical yield given as percent eeenantioselective reaction;
参考文献
McDonald, Richard I.; Wong, Gene W.; Neupane, Ram P.; Stahl, Shannon S.; Landis, Clark R.
Journal of the American Chemical Society, 2010 , vol. 132, # 40 p. 14027 - 14029
反应条件
hydrogen; (+)-DIPHOL in benzene
T=45°C; P=25857.4 Torr; 336 h; Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Becker, Y.; Eisenstadt, A.; Stille, J. K.
Journal of Organic Chemistry, 1980 , vol. 45, # 11 p. 2145 - 2151
反应条件
1: 80 percent / SOCl2 / 0.83 h / 60 °C
2: 85 percent / H2 / 10percent Pd/BaSO4 / xylene / 10 h / 110 °C
View Scheme
参考文献
Wyslouch, Aleksandra; Lisowski, Marek; Pedyczak, Artur; Siemion, Ignacy Z.
Tetrahedron: Asymmetry, 1992 , vol. 3, # 11 p. 1401 - 1410
反应条件
pyridinium p-toluenesulfonate in acetone
5 h; Heating;
参考文献
Parrinello, Giovanni; Stille, J. K.
Journal of the American Chemical Society, 1987 , vol. 109, # 23 p. 7122 - 7127
反应条件
1: toluene / 3 h / Heating
2: SOCl2 / benzene / 12 h / Heating
3: H2 / 10percent Pd/C / toluene / 2 h / 100 - 120 °C
View Scheme
参考文献
Tabuchi, Hiroyasu; Tajimi, Akitoshi; Ichihara, Akitami
Agricultural and Biological Chemistry, 1991 , vol. 55, # 10 p. 2669 - 2672
