2-(4-异丁基苯基)丙醛合成路线 （共 31 条）
反应条件
hydrogenchloride; iodine; magnesium in water
参考文献
Alcar S.R.L.
Patent: US4143229 A1, 1979 ;
反应条件
iodine; silver(l) oxide in 1,4-dioxane; water
12 h; Ambient temperature;
参考文献
Kikuchi, Haruhiko; Kogure, Katsura; Toyoda, Masashi
Chemistry Letters, 1984 , p. 341 - 344
参考文献
Hamari Chemicals, Ltd.
Patent: US4670607 A1, 1987 ;
反应条件
[rhodium(I)(N,N,N',N'-tetramethylethylenediamine)(1,5-cyclooctadiene)][rhodium(I)(1,5-cyclooctadiene)Cl2]; hydrogen in toluene
T=25°C; P=51716.2 Torr; 22 h; regioselective reaction;
参考文献
Vasylyev, Maksym; Alper, Howard
Synthesis, 2010 , # 17 art. no. C03310SS, p. 2893 - 2900
反应条件
glass wool
T=300°C; Gas phaseInert atmosphereFlow reactor; regioselective reaction;
参考文献
Ramaswamy, Govindarajan K.; Somasundaram, Angalan; Kuppuswamy, Balasubramanian K.; Velayudham, Murugesan
Journal of the Chinese Chemical Society, 2013 , vol. 60, # 1 p. 97 - 102
反应条件
1: 54 percent / potassium hydroxide, 3-tert-butyl catechol, tetrabutylammonium bromide / 1 h / 120 °C
2: H2, <Rh(CO)2Cl>2, 1,2,5-triphenylphosphole, triethylamine / toluene / 6 h / 25 °C / 15001.2 Torr
View Scheme
参考文献
Neibecker, Denis; Reau, Regis; Lecolier, Serge
Journal of Organic Chemistry, 1989 , vol. 54, # 22 p. 5208 - 5210
反应条件
1: NaBH4, CaCl2 / ethanol / -20 °C
2: 1) oxalyl chloride, DMSO, 2) Et3N / 1) -65 deg C, CH2Cl2, 5 min
View Scheme
参考文献
Chiarino; Ferrario; Pellacini; Sala
Journal of Heterocyclic Chemistry, 1989 , vol. 26, # 3 p. 589 - 593
反应条件
sodium tungstate; dihydrogen peroxide; tetra(n-butyl)ammonium hydrogensulfate
T=90°C;
参考文献
Galletti, Paola; Pori, Matteo; Giacomini, Daria
Synlett, 2010 , # 17 p. 2644 - 2648
反应条件
1.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / 0 °C
1.2: 24 h / 20 °C
2.1: tert.-butylhydroperoxide; selenium(IV) oxide / chlorobenzene; acetic acid; dichloromethane / 24 h / 20 °C
3.1: carbon tetrabromide; triphenylphosphine / dichloromethane / 8 h / 20 °C
View Scheme
参考文献
Gong, Wanchun; Liu, Yun; Xue, Jijun; Xie, Zhixiang; Li, Ying
Chemistry Letters, 2012 , vol. 41, # 12 p. 1597 - 1599
反应条件
1: tert.-butylhydroperoxide; selenium(IV) oxide / chlorobenzene; acetic acid; dichloromethane / 24 h / 20 °C
2: carbon tetrabromide; triphenylphosphine / dichloromethane / 8 h / 20 °C
View Scheme
参考文献
Gong, Wanchun; Liu, Yun; Xue, Jijun; Xie, Zhixiang; Li, Ying
Chemistry Letters, 2012 , vol. 41, # 12 p. 1597 - 1599
