2-(4-异丁基苯基)丙醛合成路线 （共 31 条）
反应条件
oxygen; Mn(II) stearate; 3-chloro-benzenecarboperoxoic acid in decane T=0°C; P=6205.8 Torr; 2 h; other reagents and solvents, var. temperature, var. pressures; Product distributionMechanism;
参考文献
Riley; Getman; Beck; Heintz
Journal of Organic Chemistry, 1987 , vol. 52, # 2 p. 287 - 290
反应条件
ethanol; horse liver alcohol dehydrogenase; NADH dipotassium salt in tetrahydrofuran pH=7.5; 24 h; aq. phosphate bufferEnzymatic reaction; enantioselective reaction;
参考文献
Galletti, Paola; Emer, Enrico; Gucciardo, Gabriele; Quintavalla, Arianna; Pori, Matteo; Giacomini, Daria
Organic and Biomolecular Chemistry, 2010 , vol. 8, # 18 p. 4117 - 4123
反应条件
oxygen; Mn(II) stearate; 3-chloro-benzenecarboperoxoic acid in decane T=0°C; P=6205.8 Torr; 2 h; other reagents and solvents, var. temperature, var. pressures; Product distributionMechanism;
参考文献
Riley; Getman; Beck; Heintz
Journal of Organic Chemistry, 1987 , vol. 52, # 2 p. 287 - 290
反应条件
1: With (1R,2R)-(+)-1,2-diphenylethylenediamine; potassium tert-butylate; hydrogen; RuCl2 in tert-butyl alcohol; hexan-1-ol T=20°C; P=15001.5 Torr; 2: With potassium permanganate; sulfuric acid in acetone T=0°C; Further stages.;
参考文献
Li, Xiaoguang; List, Benjamin
Chemical Communications, 2007 , # 17 p. 1739 - 1741
反应条件
1: With (1R,2R)-(+)-1,2-diphenylethylenediamine; potassium tert-butylate; hydrogen; RuCl2 in tert-butyl alcohol; hexan-1-ol T=20°C; P=15001.5 Torr; 2: With potassium permanganate; sulfuric acid in acetone T=0°C; Further stages.;
参考文献
Li, Xiaoguang; List, Benjamin
Chemical Communications, 2007 , # 17 p. 1739 - 1741
反应条件
1: 84.7 percent / conc. H2SO4 / 0.25 h / Ambient temperature 2: 87.2 percent / 13 percent aq. sodium hypochlorite / acetic acid; acetone / 0 °C View Scheme
参考文献
Wuts, Peter G. M.; Bergh, Carol L.
Tetrahedron Letters, 1986 , vol. 27, # 34 p. 3995 - 3998
反应条件
sodium chlorite in acetonitrile 1.) 10 deg C, 2 h, 2.) RT, 3 h;
参考文献
Babu, B. Ramesh; Balasubramaniam, K. K.
Organic Preparations and Procedures International, 1994 , vol. 26, # 1 p. 123 - 125
反应条件
hydrogenchloride; sodium hydroxide; dihydrogen peroxide
参考文献
Nisshin Flour Milling Co., Ltd.
Patent: US3965161 A1, 1976 ;
反应条件
sulfuric acid in dichloromethane; water; acetone
参考文献
Ciba-Geigy Corporation
Patent: US3950327 A1, 1976 ;
反应条件
oxygen; Mn(II) stearate; 3-chloro-benzenecarboperoxoic acid in decane T=0°C; P=6205.8 Torr; 2 h; other reagents and solvents, var. temperature, var. pressures; Product distributionMechanism;
参考文献
Journal of Organic Chemistry, , vol. 52, # 2 p. 287 - 290
