2-甲基-2-丙烯-1-醇合成路线 （共 240 条）
反应条件
toluene-4-sulfonic acid
参考文献
Barnett,M.D.; Butler,G.B.
Journal of Organic Chemistry, 1960 , vol. 25, p. 309 - 310
反应条件
aluminum oxide; dihydrogen peroxide; tungsten(VI) trioxide hydrate in water 60 deg C, 1 h; 95 deg C, 2 h;
参考文献
Chrystal, Ewan J. T.; Haines, Alan H.; Patel, Rajnikant
Carbohydrate Research, 1989 , vol. 186, p. 320 - 325
反应条件
sodium hydroxide T=140°C;
参考文献
Soc. Usines Chim. Rhone-Poulenc
Patent: GB807750 , 1957 ;
反应条件
potassium carbonate; di-μ-chloro-bis(η4-1,5-cyclooctadiene)diiridium in toluene T=20°C; 12 h;
参考文献
Kiyooka, Syun-Ichi; Ueno, Mahuyu; Ishii, Eri
Tetrahedron Letters, 2005 , vol. 46, # 27 p. 4639 - 4642
反应条件
hydrogenchloride; formic acid; sulfuric acid 1.) 100 deg C, 9 h 2.) methanol, reflux, 10 min; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Al-Khayat, Isam; Dean, Francis M.; France, Steven N.; Matkin, David A.; Orabi, Mohamed O. A.; et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985 , p. 1301 - 1310
反应条件
titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2S,3S)-tartrate in decane; dichloromethane T=-35 - -20°C; Sharpless Asymmetric Epoxidation; 28 h; Molecular sieve; enantioselective reaction;
参考文献
Schragl, Katharina M.; Forsdahl, Guro; Gmeiner, Guenter; Enev, Valentin S.; Gaertner, Peter
Tetrahedron Letters, 2013 , vol. 54, # 18 p. 2239 - 2242
反应条件
titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2S,3S)-tartrate in dichloromethane T=-30°C; 40 h; Title compound not separated from byproducts;
参考文献
Meister, Christoph; Scharf, Hans-Dieter
Liebigs Annalen der Chemie, 1983 , # 6 p. 913 - 921
反应条件
aluminum oxide; pyridinium chlorochromate in hexane 0.2 h; Ambient temperature;
参考文献
Cheng, Yu-Shia; Liu, Wen-Liang; Chen, Shu-hsia
Synthesis, 1980 , # 3 p. 223 - 224
反应条件
dihydrogen peroxide; tetra-n-butyl-ammonium in acetonitrile T=31.85°C; 13 h;
参考文献
Chemistry - A European Journal, , vol. 13, # 2 p. 639 - 648
反应条件
T=285 - 350°C; beim Leiten ueber akt.Kupfer;
参考文献
Hearne; Tamele; Converse
Industrial and Engineering Chemistry, 1941 , vol. 33, p. 807
Full Text Show Details
Shell Devel.Co.
Patent: US2042220 , 1934 ;
