暂无反应条件数据

暂无反应条件数据

暂无反应条件数据

duroquinone or galvinoxyl in further solvent(s) absence of air and moisture; slow addn. of 1.5 equiv. Bu3SnH to Hg-compd. (both in Bu3SnCl contg. radical inhibitor; 0°C) with simultaneous distn. off of product (vac.); fractional condensation (-40°C, then product at -196°C);

sodium tetrahydroborate in water addn. of NaBH4 soln. to MeHgCl soln. at pH 4; purging with He or extn. with C6D6 and drying over MgSO4; GLC, atomic absorption detection;

NaOAc in benzene-d6; acetic acid; benzene aq. acetic acid; dissoln. od the Hg compound in an acetate buffer (NaOAc/aq. HOAc, pH 3.5), addn. of C6D6 then aq. NaBH4, standing (15 min); sepn. of the benzene layer, drying (MgSO4); spectr. monitoring;