1,1,3,3-四甲基环戊烷合成路线 （共 9 条）
反应条件
hydrogen; nickel
T=150°C;
参考文献
Slomp,G. et al.
Journal of Organic Chemistry, 1960 , vol. 25, p. 514 - 518
反应条件
potassium hydroxide; hydrazine hydrate; diethylene glycol
参考文献
Gault; Germain
Bulletin de la Societe Chimique de France, 1959 , p. 1365,1367, 1370
反应条件
1: Ba(OH)2, MnCO3 / 250 - 255 °C
2: H2 / Ni / 200 °C
3: Al2O3 / 300 °C
4: H2 / Ni / 150 °C
View Scheme
参考文献
Slomp,G. et al.
Journal of Organic Chemistry, 1960 , vol. 25, p. 514 - 518
反应条件
1: Al2O3 / 300 °C
2: H2 / Ni / 150 °C
View Scheme
参考文献
Slomp,G. et al.
Journal of Organic Chemistry, 1960 , vol. 25, p. 514 - 518
反应条件
tri-n-butyl-tin hydride in xylene
参考文献
Beckwith,A.L.J.; Lawrence,T.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1979 , p. 1535 - 1539
反应条件
1: LiAlH4 / diethyl ether
2: (i) NaH, imidazole, THF, (ii) /BRN= 1098293/, (iii) /BRN= 969135/
3: nBu3SnH / xylene
View Scheme
参考文献
Beckwith,A.L.J.; Lawrence,T.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1979 , p. 1535 - 1539
反应条件
1: (i) NaH, imidazole, THF, (ii) /BRN= 1098293/, (iii) /BRN= 969135/
2: nBu3SnH / xylene
View Scheme
参考文献
Beckwith,A.L.J.; Lawrence,T.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1979 , p. 1535 - 1539
反应条件
1: dimethyl sulfate; sodium tert-pentylate
2: hydrazine hydrate; potassium hydroxide; diethylene glycol
View Scheme
参考文献
Gault; Germain
Bulletin de la Societe Chimique de France, 1959 , p. 1365,1367, 1370
反应条件
hydrogen; iridium
T=126.9°C; 2 h; various temp., molar ratioand metal films; usage of D2; Product distributionMechanism;
参考文献
Finlayson, Odilla E.; Clarke, John K. A.; Rooney, John J.
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1984 , vol. 80, p. 191 - 210
