1: With peracetic acid; acetic acid in water T=-5 - 20°C; 1.5 - 2 h; 2: With palladium dihydroxide in water T=15 - 20°C; 2 h; 3: With hydrogen in water; butan-1-ol T=20 - 25°C; P=2585.81 Torr; 3 h; Product distribution / selectivity;
参考文献
Cox, D. Phillip; Zhang, Yong
Patent: US2008/132703 A1, 2008 ;
Location in patent: Page/Page column 5-6 ;
1: With dihydrogen peroxide; oxalic acid; acetic acid in water T=20°C; 2: With sodium hydroxide in water T=2°C; pH=9.2; Product distribution / selectivity;
1: With formic acid; sulfuric acid; dihydrogen peroxide in water T=20°C; 16 h; 2: With 5 palladium on charcoal in water T=20 - 60°C; 20 h; 3: With ammonium hydroxide T=20°C; pH=9.5; 1 h; Overall yield = 2.33 g;
1: With biscyclopentadienyliron(II) in chloroform T=40°C; 5 h; 2: With hydrogenchloride in chloroform; water T=50°C; 1 h; 3: With ammonium hydroxide in dichloromethane; chloroform; water pH=7 - 9;
参考文献
Kok, Gaik B.; Pye, Cory C.; Singer, Robert D.; Scammells, Peter J.
Journal of Organic Chemistry, 2010 , vol. 75, # 14 p. 4806 - 4811
